Oxidation of S(Ⅳ)to S(Ⅵ)in the effluent of a flue gas desulfurization(FGD)system.is very critical for industrial applications of seawater FGD.This paper reports a pulsed corona discharge oxidation process combined with a TjO_2 photocatalyst to convert S(Ⅳ)to S(Ⅵ)in artificial seawater.Experimental results show that the oxidation of S(Ⅳ)in artificial seawater is enhanced in the pulsed discharge plasma process through the application of Ti02coating electrodes.The oxidation rate of S(IV)using Ti metal as a ground electrode is about2.0x10^(-4)mol·L^(-1)·min^(-1),the oxidation rate using TiO_2/Ti electrode prepared by annealing at500℃in air is 4.5x10^(-4)mol·L^(-1)·min^(-1),an increase with a factor 2.25.The annealing temperature for preparing TiO_2/Ti electrode has a strong effect on the oxidation of S(Ⅳ)in artificial seawater.The results of in-situ emission spectroscopic analysis show that chemically active species(i.e.hydroxyl radicals and oxygen radicals)are produced in the pulsed discharge plasma process.Compared with the traditional air oxidation process and the sole plasma-induced oxidation process,the combined application of TiO_2 photocatalysts and a pulsed high-voltage electrical discharge process is useful in enhancing the energy and conversion efficiency of S(Ⅳ)for the seawater FGD
