Bilayer humidity-responsive actuators are generally composed of actuating and supporting layers of different materials with largely different wettability.Such kinds of bilayer actuators suffer from low adhesive force between the two layers during usage.This study demonstrates the preparation of humidity-responsive bilayer actuators that have the same materials in the actuating and supporting layers to avoid the adhesive issue.The bilayer actuators consist of a porous poly(acrylic acid)(PAA)/poly(allylamine hydrochloride)(PAH)layer and a nonporous PAA/PAH layer that are fabricated by exponentially layer-by-layer assembly method.At a high/low relative humidity(RH),the nonporous PAA/PAH layer can efficiently expand/shrink by absorbing/desorbing water while the volume expansion/shrinkage of the porous PAA/PAH layer in an environment with changed humidity is significantly suppressed by the micrometer-sized pores.The largely different expansion/shrinkage of the nonporous and porous PAA/PAH layers when subjected to humidity changes enables rapid and reversible rolling/unrolling motions of the bilayer actuator.The bilayer actuator shows a faster rolling speed and a larger bending curvature when subjected to a larger humidity increase.
The fabrication of smart films with reversible wettability enabled by the stimulus-induced morphology changes has attracted growing interest but remains a challenge. Here we report a smart film that can reversibly changes its wettability between transparent hydrophobicity to translucent superhydrophobicity through the humidity-induced wrinkling/de-wrinkling process.The film was fabricated by depositing hydrophobic SiO2 nanoparticles(NPs) on poly(acrylic acid)(PAA)/poly(allylamine hydrochloride)(PAH) films, followed by partially exfoliating the films from the underlying substrates. The partially exfoliated PAA/PAH film can reversibly wrinkle and de-wrinkle when being alternately subjected to humid and dry environments. The deposition of hydrophobic SiO2 NPs on the wrinkling PAA/PAH film does not hinder the humidity-enabled wrin-kling/de-wrinkling ability of the composite film. The hydrophobic SiO2 NPs and the underlying humidity-wrinkling PAA/PAH film enable the composite film to spontaneously change from hydrophobic and transparent to superhydrophobic and translucent with the rise of environmental humidity.
