ZnO nanorods were grown on Si substrate by hydrothermal method under various reaction time (12, 24, and 36 h), Zn2+ concentrations (0.01, 0.02, and 0.05 mol/L) and reaction temperatures (70-95 ℃ ). Their photoluminescence (PL) tests were taken at room temperature. Nanorods grown under longer reaction times or higher temperatures can emit stronger UV light and depressed green light, suggesting better crystallization of ZnO nanorods. Higher Zn2+ concentration results in stronger green band emitting, whereas the UV peak is depressed with the Zn2+ concentration over 0.02 mol/L. This indicates that excessive interstitial Zn defects may be introduced into the nanorods in Zn-rich environment.
HU Ming,ZHANG Xia,MENG Xianquan School of Physics and Technology,Wuhan University,Wuhan 430072,Hubei,China
