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国家自然科学基金(51271155)

作品数:40 被引量:53H指数:4
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40 条 记 录,以下是 1-10
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低温耐辐照环氧树脂复合绝缘材料制备及性能研究
为了使超导线圈能更好的运用于高温超导磁体中,起电气绝缘、冷却、机械支撑、固定和保护超导体作用的绝缘材料必不可少。环氧树脂因其具有优良的加工成型性能、电绝缘性、耐腐蚀性及优异的机械性能等而用作主要的绝缘材料。然而环氧树脂具...
邹小凤
关键词:环氧树脂氮化铝氰酸酯介电性能
Structure and properties of CIGS films based on one-stage RF-sputtering process at low substrate temperature被引量:1
2014年
Currently, Nanjing South Railway Station planning to implement slate roof renovation is integrating solar cell modules into traditional roof materials to generate clean energy. Copper–indium–gallium diselenide(CuIn1-xGaxSe2, CIGS) is one of the most promising materials for thin film solar cells. Cu(In1-xGax)Se2films were deposited by a one-step radio frequency magnetron sputtering process at low substrate temperature. X-ray diffraction, Raman, scanning electron microscopy, energydispersive X-ray spectroscopy, and electrical and optical measurements were carried out to investigate the deposited films. The results reveal that a temperature of 320 °C is critical for near-stoichiometric CIGS films with uniform surface morphology. Cu-rich phase particulates are found at less than this temperature. The sample deposited at380 °C gives well-crystalline single-phase CIGS film.Furthermore, the electrical and optical performances of the absorber layer are improved significantly with the increasing substrate temperature.
Yong YanShasha LiYufeng OuYaxin JiChuanpeng YanLian LiuZhou YuYong Zhao
关键词:衬底温度CIGS工艺性能
Transport properties and microstructure of La_(0.7)Sr_(0.3)MnO_3 nanocrystalline thin films grown by polymer-assisted chemical solution deposition被引量:1
2014年
Perovskite-based materials can be widely used in the aerospace and transportation field. Perovskite manganese oxides La0.7Sr0.3MnO3(LSMO) thin films were grown on LaAlO3(100) and Si(100) single crystal substrates by the polymer-assisted chemical solution deposition(PACSD) method. Electronic transport behavior,microstructure, and magnetoresistance(MR) of LSMO thin films on different substrates were investigated. The resistance of LSMO films fabricated on LaAlO3substrates is smaller than that on the Si substrates. The magnetic field reduces resistance of LSMO films both on Si and LAO in the wide temperature region, when the insulator-metal transition temperature shifts to higher temperature. The low-field magnetoresistance of LSMO films on Si in low temperature range at 1 T is larger than that of LSMO films on LAO. However, the MR of LSMO film on LAO films at room-temperature is about 5.17 %. The thin films are smooth and dense with uniform nanocrystal size grain.These results demonstrate that PACSD is an effective technique for producing high quality LSMO films, which is significant to improve the magnetic properties and the application of automotive sensor.
Min ZhangLi LvZhantao WeiXinsheng YangXin Zhang
关键词:纳米晶薄膜SI(100)LSMO低场磁电阻
The preparation process and feature of the topological insulator Bi_2Te_3被引量:1
2014年
Topological insulators are insulating in the bulk but have metallic surface states. Its unique physicochemical properties can find numerous applications in electronics, spintronics, photonics, the energy sciences, and the signal control of transportation. We report an experimental approach to synthesize the high-quality single crystal of topological insulator Bi2Te3by using self-flux method. We obtained the optimal preparation conditions by adjusting the parameters of heat treatment, and successfully prepared the single-crystal Bi2Te3sample. The as-grown samples have a surface with bright metallic luster and are soft and fragile. Furthermore, Bi2Te3has the obvious layer structure from SEM results. The data of X-ray diffraction and scanning electron microscope show that Bi2Te3single crystal grows along the c-axis with the order of Te(1)–Bi–Te(2)–Bi–Te(1)and crystallizes in the hexagonal system with space group of R/3 m. The q–T curve shows that q decreases with temperature, showing metallic behavior over the whole temperature range.
Peng ChenDajin ZhouPingyuan LiYajing CuiYongliang Chen
关键词:BI2TE3
DC and AC transport properties on La_(0.8)Sr_(0.2)MnO_3
2014年
Magnetoresistive sensor can be widely used in modern transportation field, such as the vehicle positioning and navigation system, vehicle detection system, and intelligent transportation system. In order to improve the efficiency of magnetoresistive sensor, we synthesized La0.8Sr0.2MnO3polycrystalline bulks at different sintering temperatures and investigated their DC and AC transport properties in this work. As a result, all samples showed insulator–metal(I–M) phase transition, and the transition temperature(TI–M) shifted to higher temperature with the increase of sintering temperature. The TI–Mmeasured at different AC frequencies was smaller than that measured at DC condition, which implied that the I–M phase transition was suppressed at AC frequencies. The resistivity measured at high AC frequencies was larger than that measured at low AC frequencies, which could be attributed to the change of the magnetic penetration depth(d). However, the room-temperature AC-magnetoresistance(MR) at low frequencies was much larger than that at high frequencies and room-temperature DC-MR. These findings demonstrate that reducing the AC frequency is an effective way for enhancing the room-temperature MR, which can be used to promote the efficiency of magnetoresistive sensor.
Zhantao WeiXinsheng YangLi LvMin ZhangYong Zhang
关键词:LA0输运性质磁阻传感器车辆检测系统烧结温度
Cl掺杂对n-Cu2O的光电性能的影响被引量:4
2016年
在酸性溶液中利用恒电位沉积法在导电玻璃(ITO)上沉积Cu_2O薄膜,并以KCl为添加剂对其进行掺杂,采用场发射扫描电子显微镜(FESEM)和X射线衍射谱(XRD)等手段研究了氯掺杂对Cu_2O表面形貌和晶体结构的影响。紫外-可见吸收光光谱确定得到的Cu_2O和Cl掺杂Cu_2O(Cu_2O-Cl)样品的禁带宽度分别为1.98和1.95eV。根据表面光电压谱和相位谱,掺杂前后的Cu_2O均为n型,Cu_2O-Cl有更强的表面光电压响应。场诱导表面光电压谱结果表明未掺杂Cl的Cu_2O在加负偏压时易形成反型层;氯离子的掺杂引入杂质能级可以提高n型导电性。光电化学性能测试发现,以Cu_2O、Cu_2O-Cl为光阳极组成的光化学太阳电池,在大气质量AM 1.5G、100mW/cm^2标准光强作用下光电转换效率分别为0.12%和0.51%。
谢思思鲁双伟马文利杨峰席金芳邹龙生蔡芳共程翠华赵勇阚香张勇
关键词:CU2O表面光电压谱光电化学性能
拓扑超导体FeSexTe1-x单晶超导性能与磁通钉扎
2020年
铁基超导体FeSexTe1-x由于其具有上临界场高、各向异性小、临界电流密度大等优点,备受研究者的广泛关注.本文采用自助溶剂法生长得到了几种Se/Te组分比例不同的FeSexTe1-x单晶样品,对其结构和形貌进行了表征,并且对样品在低温下的磁性进行了测量.对样品超导态下临界电流密度、磁通钉扎力和磁场的关系进行了分析,讨论了样品在低温下的磁通钉扎模式.通过分析Se和Te的不同比例对上述性能的影响,确定了超导性能最佳的组分,为今后进一步研究FeSexTe1-x的超导与拓扑性质提供了参考.
梁超张洁赵可羊新胜赵勇
关键词:临界电流密度磁通钉扎
氩气退火时间对Fe(Se,Te)薄膜的性能影响研究
2022年
作为一种铁基超导薄膜,Fe(Se,Te)薄膜具有晶体结构简单、所包含的元素较少、易于合成的特点,不仅有利于超导机理研究而且有着潜在的技术应用价值。本文通过磁控溅射在温度为320℃的CaF_(2)单晶衬底上制备了Fe(Se,Te)薄膜,并在氩气氛围下进行了退火处理。研究了退火时间对Fe(Se,Te)薄膜的晶体结构、微观形貌、成分组成以及电输运特性的影响。结果表明:Fe(Se,Te)薄膜的结晶性较好,退火有助于消除薄膜样品中的FeSe相,薄膜的晶格常数c对退火不敏感,退火后薄膜晶粒尺寸变大;Fe(Se,Te)薄膜成分与靶材的名义组分存在一定的偏差,退火时间越长,Fe(Se,Te)薄膜表面的颗粒越密集;Fe(Se,Te)薄膜的电阻随温度升高而减小,呈现出半导体特性,退火3 h后电阻明显增大。
罗露林张洁羊新胜赵勇
关键词:电输运特性
强关联效应下非磁性元素Ir掺杂的SmFeAsO电子结构理论研究
2013年
基于密度泛函理论,采用广义梯度近似方法(SGGA+U)计算分析了SmOFeAs电子结构以及Ir掺杂对该体系晶体结构和电子结构的影响.结果表明,随着Ir的掺杂,SmOFeAs晶体结构中FeAs层与SmO层之间的耦合增强,晶体内部所含的铁砷四面体随着Ir掺杂其畸变性程度逐步减小.Fe3d以及As4p杂化轨道对体系电子结构起主要影响作用.Ir掺杂所引入的电子使FeAs层的巡游电子增多、Fe3d轨道中的dz2轨道离域性增强.当Ir掺杂量为20%时,费米面处于电子态密度峰值附近,费米面急剧变化使该体系的Tc值有所增高,反映了体系费米能级移动与其超导电性的密切关联性.计算的电子态密度与XPS所得价带谱实验结果一致,进一步验证了采用SGGA+U方法其包含修正d轨道局域电子的库仑势,使得计算结果与实验结果更加接近.
潘敏黄整赵勇
关键词:晶体结构电子结构
无铅焊料制备的Y0.5Gd0.5Ba2Cu3O7-z涂层超导带材搭接接头的机电性能研究
2021年
由于单根Y0.5Gd0.5Ba2Cu3O7-z(YGdBCO)涂层超导带材的长度有限,因此在制造高温超导(HTS)器件时不可避免地需要接头。HTS设备的稳定运行在很大程度上取决于接头的品质,因为接头的机电性能通常低于母材。本研究应用Sn42Bi58焊料制作YGdBCO涂层超导带材搭接接头。与传统的Sn60Pb40焊料相比,无铅Sn42Bi58焊料对环境友好,且熔点降低了40℃,因此可在低于150℃的低温下进行焊接操作,有助于抑制超导带材在连接过程中的性能下降。通过测量自场和液氮温度下的电压-电流曲线,研究了加载压力,加压速度和搭接长度对YGdBCO接头临界电流,电阻和n值的影响。通过优化焊接技术,可在12.5 MPa的压强和50 N/s的加压速度下重复获得与母材临界电流相当的25 cm长的低阻接头,其电阻为4.35~5.58 nΩ。还对轴向拉伸作用下接头的力学行为进行了研究,单根带材和接头部分的临界轴向拉伸力分别为213和212 N。上述结果表明,与传统焊接技术相比,采用优化的无铅Sn42Bi58焊料制备低电阻、高拉伸特性的焊接接头的稳定性和重复性明显提升,为YGdBCO超导带材大规模运用的接头连接提供了一种有前景的选择。
杨淦淞王文涛刘连王明江田正健郑秋瞳赵勇
关键词:临界电流
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