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国家自然科学基金(21206153)

作品数:25 被引量:165H指数:8
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25 条 记 录,以下是 1-10
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不同臭氧组合工艺处理含硝基苯类化合物废水的实验研究被引量:16
2014年
为研究臭氧高级氧化技术对含硝基苯类化合物炸药废水的处理效果,采用四种不同组合工艺(旋转填料床(RPB)-O3/H2O2、RPB-O3、曝气反应装置(BR)-O3/H2O2和BR-O3),进行了模拟废水中硝基苯类化合物降解的对比性试验。结果表明,O3/H2O2工艺对硝基苯类化合物表现出较强的降解性能,去除率可达99%,出水指标达到《污水综合排放标准》(GB8978-1996)中硝基苯类化合物排放标准。在相同反应时间下,BR-O3/H2O2和BR-O3工艺对硝基苯类化合物去除率明显偏低。在RPB-O3/H2O2和RPB-O3工艺中,硝基苯类化合物去除率随超重力因子和初始p H值的增加而增大,而随双氧水浓度和液体流量的增加呈先增大后降低的变化趋势。在臭氧浓度为50 mg·L-1,超重力因子为80,初始p H为10.5,双氧水浓度4.9 mmol·L-1和液体流量120 L·h-1的试验条件下,硝基苯类化合物去除效果较好。此条件下硝基苯类化合物的降解过程符合假一级反应动力学。
郭亮焦纬洲刘有智许承骋刘文丽李静
关键词:环境化学硝基苯类化合物超重力臭氧双氧水
Mass transfer characteristics in a rotating packed bed with split packing被引量:4
2015年
The rotating packed bed (RPB) with split packing is a novel gas-liquid contactor, which intensifies the mass transfer processes controlled by gas-side resistance. To assess its efficacy, the mass transfer characteristics with adjacent rings in counter-rotation and co-rotation modes in a split packing RPB were studied experimentally. The physical absorption system NH3-H2O was used for characterizing the gas volumetric mass transfer coeffi- cient (kyae) and the effective inteffacial area (ae) was determined by chemical absorption in the CO2-NaOH sys- tem. The variation in kyae and ae with the operating conditions is also investigated. The experimental results indicated that kyae and ae for counter-rotation of the adjacent packing rings in the split packing RPB were higher than those for co-rotation, and both counter-rotation and co-rotation of the split packing RPB were superior over conventional RPBs under the similar ooerating conditions.
Youzhi LiuDeyin GuChengcheng XuGuisheng QiWeizhou Jiao
乳化蜡的制备及应用进展被引量:12
2012年
介绍了乳化蜡的制备方法及制备条件,主要包括乳化剂、乳化温度、乳化时间及搅拌速度等对乳化蜡稳定性等性能的影响;综述了乳化蜡在纺织、人造板、造纸、农业、乳化炸药等领域的应用情况;并对国内乳化蜡的发展前景进行了简单的展望。
李静焦纬洲刘有智刘文丽
关键词:表面活性剂乳化蜡乳化
Effects of Airflow Field on Droplets Diameter inside the Corrugated Packing of a Rotating Packed Bed被引量:4
2014年
Rotating packing bed(RPB) has a better mixing performance than traditional mixers and shows potential application in the petroleum industry. However, acquisition of information about the mixing process directly through experiments is difficult because of the compact structure and complex multiphase flow pattern in RPB. To study the mixing characteristic, Fluent, the computational fluid dynamics(CFD) software, was used to explore the effect of airflow field on droplet diameter. For conducting calculations, the gas-liquid two-phase flow inside the packing was simulated with the RNG k-ε turbulence model and the Lagrange Discrete Phase Model(DPM), respectively. The numerical calculation results showed that coalescence and breakup of droplets can take place in the gas phase flow inside the packing and can be strengthened with increased rotating speed, thereby leading to the enlargement of the average diameter.
Xu ChengchengJiao WeizhouLiu YouzhiGuo LiangYuan ZhiguoZhang Qiaoling
关键词:ROTATINGBEDGAS-LIQUIDMIXING
Dispersion Performance of Methanol-Diesel Emulsified Fuel Prepared by High Gravity Technology被引量:2
2014年
A new continuous process for preparing methanol-diesel emulsified fuel with an Impinging Stream-Rotating Packed Bed is proposed. The droplet size of dispersed phase(methanol) of the emulsified fuel has a significant effect on the combustion of methanol-diesel emulsified fuel. In this paper, the methanol-diesel emulsified fuel uses diesel as the continuous phase and methanol as the dispersed phase. The Sauter mean diameter of the dispersed phase of methanol-diesel emulsified fuel was characterized with microphotography and arithmetic method. The experimental result showed that the Sauter mean diameter of the dispersed phase, which was decreased with the augmentation of the high gravity factor, liquid flow rate and emulsifier dosage, was inversely proportional to the methanol content. The Sauter mean diameter of the dispersed phase can be controlled and adjusted in the range of 12—40 μm through the change of operating conditions. The correlative expressions of the Sauter mean diameter of emulsified fuel were obtained and the calculated values agreed well with the experimental values.
Jiao WeizhouLi JingLiu YouzhiZhang QiaolingLiu WenliXu ChengchengGuo Liang
关键词:EMULSIONDISPERSION
Degradation of Nitrobenzene-Containing Wastewater with O_3 and H_2O_2 by High Gravity Technology被引量:17
2013年
Nitrobenzene-containing industrial wastewater was degraded in the presence of ozone coupled with H2O2 by high gravity technology. The effect of high gravity factor, H2O2 concentration, pH value, liquid flow-rate, and reaction time on the efficiency for removal of nitrobenzene was investigated. The experimental results show that the high gravity technology enhances the ozone utilization efficiency with O3/H202 showing synergistic effect. The degradation efficiency in terms of the COD removal rate and nitrobenzene removal rate reached 45.8% and 50.4%, respectively, under the following reaction conditions, viz.: a high gravity factor of 66.54, a pH value of 9, a H2O2/O3 molar ratio of 1:1, a liquid flow rate of 140 L/h, an ozone concentration of 40 rag/L, a H2O2 multiple dosing mode of 6 mL/h, and a reaction time of 4 h. Compared with the performance of conventional stirred aeration mixers, the high gravity technology could increase the COD and nitrobenzene removal rate related with the nitrobenzene-containing wastewater by 22.9% and 23.3%, respectively.
Jiao WeizhouLiu YouzhiLiu WenliLi JingShao FanWang Chaoran
关键词:OZONEH2O2
甲醇柴油乳液稳定性研究被引量:3
2014年
在20℃下,研究了复配乳化剂及助乳化剂的含量、HLB值、甲醇含量、乳化时间及转速等对甲醇柴油乳液稳定性的影响规律。研究结果表明,随着复配乳化剂及助乳化剂的含量、HLB值和转速的增大,乳液的稳定性呈现先升高后降低的趋势。随着乳化时间的延长,稳定性先升高后趋于基本稳定。随着甲醇含量的增大,乳液的稳定性逐渐降低。实验得到的适宜操作参数:乳化时间为2 min、转速为5×2 800 r·min-1、HLB值为4.5、乳化剂及助乳化剂质量分数均为3%、甲醇质量分数为15%。测得Sauter平均直径D=13μm。
李静焦纬洲刘有智刘文丽许承骋郭亮
关键词:稳定性
超声强化铁碳微电解处理硝基苯废水被引量:6
2016年
针对铁碳微电解处理有机废水时铁碳填料易钝化、难连续可用性的问题,采用超声波(US)-零价铁/活性炭(Fe0/GAC)微电解技术降解硝基苯废水。考察了铁碳填料连续使用性,考察了Fe0剂量、GAC剂量、废水初始p H值对US-Fe0/GAC降解硝基苯的影响规律。结果表明:不更换填料时,US-Fe0/GAC连续处理4批相同废水的硝基苯去除率均在90%左右;而在Fe^0/GAC处理下,4次硝基苯去除率依次为48%、36%、25%、17%。超声不仅维持了填料高活性使其能被连续使用,有效提高了Fe^0/GAC对硝基苯去除率。得到降解硝基苯的适宜操作条件为:Fe0剂量20 g·L^(-1),GAC剂量10 g·L^(-1),废水初始p H为4。在此条件下,反应80min,硝基苯的去除率可达93%,出水的可生化系数BOD5/CODcr为0.32,能满足生化处理要求。
余丽胜焦纬洲刘有智李苏霖李傲雯张敏
关键词:微电解硝基苯零价铁
高级氧化法中H_2O_2对COD的测定影响及消除被引量:4
2014年
通过测定含不同H2O2浓度的纯水体系及硝基苯类化合物水样体系的废水化学需氧量(COD),分析发现硝基苯类化合物水样中H2O2对COD的测量存在正干扰,且具有很好的线性关系。在不引入新的干扰前提下,探讨了相应的H2O2消除方法。结果表明,当水样中H2O2浓度475 mg·L-1,COD值为747.6 mg·L-1时,改变水样p H值为碱性有利于H2O2的去除;添加二氧化锰催化剂虽然能在较短时间内去除H2O2,但可能引入新的干扰物;添加过氧化氢酶在不引入新的干扰情况下可快速去除H2O2。当反应时间3 min,分别调节水样p H为12、添加二氧化锰、添加过氧化氢酶,水样中H2O2去除率为1.2%、45.6%、100%。在相同酶量下处理含不同浓度H2O2的水样,H2O2均可在短时间内被除净。分析表明,添加过氧化氢酶可为快速、高效消除废水中未知浓度H2O2对CODCr测定的影响提供一条新的途径。
郭亮焦纬洲刘有智许承骋刘文丽李静
关键词:环境化学硝基苯类化合物H2O2
强化臭氧传质的研究进展被引量:8
2017年
臭氧高级氧化法具有高效、无二次污染等优势,广泛用于各类废水处理,而臭氧在气液界面传质效率低增加了运行成本.依据臭氧传质理论,从改进气液两相接触器结构、加入促传剂、外场强化等方面综述了臭氧传质的研究现状及强化机理,并展望了强化臭氧传质的发展方向.
秦月娇焦纬洲杨鹏飞刘有智
关键词:臭氧高级氧化法传质废水
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