The effect of Sn on corrosion behavior of ferritic stainless steels in 20mass% H_2SO_4 was investigated by alternating current and direct current electrochemical methods and gravimetric tests at 25 ℃.The results show that Sn can effectively improve general corrosion resistance of ferritic stainless steels in H_2SO_4,mainly due to highly raised hydrogen evolution overpotential which is in favour of strong suppression of hydrogen evolution reaction,and inhibitive effect of dissolved Sn^(2+)on elementary anodic reactions.With increasing Sn content,the better corrosion resistance can be reached.The Electrochemical Impedance Spectroscopy(EIS)includes four time constants and can be perfectly fitted by equivalent circuit:R_s(C_(dl)R_(ct))(Q_(ads)R_(ads)(R_(L1)(L_1(R_(L2)L_2)))).
The hot deformation behavior of ultra purified 17% Cr ferritic stainless steel stabilized with Nb and Ti was investigated using axisymmetric hot compression tests on a thermomechanical simulator.The deformation was carried out at the temperatures ranging from 700 to 1 100℃ and strain rates from 1to 10s-1.The microstructure was investigated using electron backscattering diffraction.The effects of temperature and strain rate on deformation behavior were represented by Zener-Hollomon parameter in an exponent type equation.The effect of strain was incorporated in the constitutive equation by establishing polynomial relationship between the material constants and strain.A sixth order polynomial was suitable to represent the effect of strain.The modified constitutive equation considering the effect of strain was developed and could predict the flow stress throughout the deformation conditions except at800℃in 1s-1 and at 700℃in 5and 10s-1.Losing the reliability of the modified constitutive equation was possibly ascribed to the increase in average Taylor factor at 800℃in 1s-1 and the increase in temperature at 700℃in 5and10s-1 during hot deformation.The optimum window for improving product quality of the ferritic stainless steels was identified as hot rolling at a low finisher entry temperature of 700℃,which can be achieved in practical production.
Texture inhomogeneity usually takes place in ferritic stainless steels due to the lack of phase transformation and recrystallization during hot strip rolling,which can deteriorate the formability of final sheets.In order to work out the way of weakening texture inhomogeneity,conventional hot rolling and warm rolling processes have been carried out with an ultra purified ferritic stainless steel.The results showed that the evolution of through-thickness texture is closely dependent on rolling process,especially for the texture in the center layer.For both conventional and warm rolling processes,shear texture components were formed in the surface layers after hot rolling and annealing;sharp α-fiber and weakγ-fiber with the major component at{111}<110> were developed in both cold rolled sheet surfaces,leading to the formation of inhomogeneousγ-fiber dominated by{111}<112>after recrystallization annealing.In the center layer of conventional rolled and annealed bands,strongα-fiber and weakγ-fiber textures were formed;the cold rolled textures were comprised of sharpα-fiber and weakγ-fiber with the major component at{111}<110>,and inhomogeneousγ-fiber dominated by{111}<112> was formed after recrystallization annealing.By contrast,in the centre layer of warm rolled bands,the texture was comprised of weakα-fiber and sharpγ-fiber,andγ-fiber became the only component after annealing.The cold rolled texture displayed a sharpγ-fiber with the major component at{111}<112>and the intensity ofγ-fiber close to that ofα-fiber,resulting in the formation of a nearly homogeneousγ-fiber recrystallization texture in the center layer of the final sheet.
