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中国博士后科学基金(20110490539)

作品数:3 被引量:24H指数:2
相关作者:王铁冠常象春程斌袁媛王宁更多>>
相关机构:中国石油大学(北京)山东科技大学更多>>
发文基金:中国博士后科学基金教育部科学技术研究重点项目更多>>
相关领域:石油与天然气工程天文地球更多>>

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C_5—C_7轻烃在原油地球化学研究中的应用——以塔北隆起哈拉哈塘凹陷奥陶系原油为例被引量:13
2013年
以C5—C7轻烃化合物为工具进行原油成熟度、烃源岩有机质类型、原油生成温度等方面的地球化学研究。哈拉哈塘凹陷奥陶系原油样品庚烷值和异庚烷值分别为31.0~38.3及1.0~2.5,均值分别为36.0及2.2,据此得出样品属于高成熟油,烃源岩有机质类型为Ⅰ型和Ⅱ型。原油样品C5—C7轻烃馏分相对组成以正烷烃占优势,C7轻烃化合物相对组成以异构烷烃占优势,推测原油样品烃源岩以腐泥型有机质为主。样品Mango稳态催化轻烃参数K1值为0.97~1.07,均值为1.03,符合K1值相对稳定性规律,K2值为0.18~0.22,均值为0.20,符合海相原油特点;样品具有3RP和6RP,推测烃源岩以腐泥型有机质为主;原油生成温度为119.0~125.9℃。
程斌王铁冠常象春
Geochemical analysis of mixed oil in the Ordovician reservoir of the Halahatang Depression,Tarim Basin,China被引量:2
2013年
In this study,12 crude oil samples were collected and analyzed from the Ordovician reservoir in the Halahatang Depression,Tarim Basin,China.Although the density of oil samples varies considerably,based on saturated hydrocarbon gas chromatographic(GC),saturated and aromatic hydrocarbon gas chromatographic-mass spectrometric(GC/MS) and stable carbon isotopic composition analyses,all the samples are interpreted to represent a single oil population with similar characteristics in a source bed or a source kitchen,organic facies and even in oil charge history.The co-existence of a full suite of n-alkanes and acyclic isoprenoids with UCM and 25-norhopanes in the crude oil samples indicates mixing of biodegraded oil with fresher non-biodegraded oil in the Ordovician reservoir.Moreover,according to the conversion diagram of double filling ratios for subsurface mixed crude oils,biodegraded/non-biodegraded oil ratios were determined as in the range from 58/42 to 4/96.Based on oil density and oil mix ratio,the oils can be divided into two groups:Group 1,with specific density>0.88(g/cm3) and oil mix ratio>1,occurring in the north of the Upper Ordovician Lianglitage and Sangtamu Formation pinchout lines,and Group 2,with specific density<0.88(g/cm3) and oil mix ratio<1,occurring in the south of the pinchout lines.Obviously,Group 2 oils with low densities and being dominated by non-biodegraded oils are better than Group 1 oils with respect to quality.It is suggested that more attention should be paid to the area in the south of the Upper Ordovician Lianglitage and Sangtamu Formation pinchout lines for further exploration.
CHENG BinWANG TieguanCHANG Xiangchun
关键词:地球化学分析奥陶系混合油生物降解油
塔北哈6井油砂及沥青砂岩抽提物的地球化学特征及对比被引量:9
2014年
采集塔里木盆地哈拉哈塘凹陷哈6井石炭系油砂及志留系沥青砂岩样品共5件,对其抽提并进行稳定碳同位素、饱和烃气相色谱及色谱/质谱等分析。石炭系油砂与志留系沥青砂岩抽提物的稳定碳同位素组成十分相似;CPI值为0.95~1.06,OEP值为0.94~1.00,姥鲛烷/植烷值为0.34~0.76;C21/C23三环萜烷为0.37~0.47,C29/C30藿烷为0.91~0.97,C35 S/C34 S藿烷为0.91~1.00,伽马蜡烷/C30藿烷为0.69~0.79,Ts/( Ts+Tm)为0.39~0.43,C27、C28、C29规则甾烷及芴、硫芴、氧芴的相对组成均非常接近。样品抽提物中正烷烃和类异戊二烯烃与25-降藿烷系列化合物和UCM鼓包共存。分析认为石炭系与志留系原油源自相同的烃源岩,两者均存在多期充注且遭受了不同程度的生物降解作用。
程斌王铁冠常象春袁媛王宁
关键词:油砂沥青砂岩抽提物石炭系志留系塔里木盆地
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