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国家自然科学基金(20897010)

作品数:3 被引量:8H指数:2
相关作者:胡正君史亚利蔡亚岐更多>>
相关机构:中国科学院生态环境研究中心更多>>
发文基金:国家自然科学基金国家重点基础研究发展计划更多>>
相关领域:环境科学与工程农业科学更多>>

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环境水样中人工合成麝香的分析方法
2010年
采用C18萃取盘富集净化结合气相色谱-质谱联用技术(GC-MS),建立了测定城市污水和河水中5种多环麝香和2种硝基麝香的分析方法.水样经C18萃取盘富集后,用正己烷及正己烷、二氯甲烷混合溶剂进行洗脱,洗脱液经浓缩定容后用GC-MS选择离子监测模式(SIM)进行检测,使用AHTN-d3作为替代物标样,其回收率为89.7%—104.9%.以六氯苯-13C为内标进行定量,7种合成麝香的线性范围为0.001—1μg·ml-1,样品方法检出限在1.0—1.2ng·l-1(S/N=5).做空白加标实验和基质加标回收实验,空白加标回收率及实际样品平均加标回收率均在78.6%—106.3%范围内,相对标准偏差在3.9%—8.4%之间;方法准确,快速,简便,可以用于实际水样中合成麝香的检测。
胡正君史亚利蔡亚岐
关键词:合成麝香环境水样GC-MS
Primary investigation of the pollution status of polycyclic aromatic hydrocarbons (PAHs) in water and soil of Xuanwei and Fuyuan,Yunnan Province,China被引量:4
2009年
Lung cancer incidence in Xuanwei and Fuyuan is extremely high. The air pollution, especially indoor airborne PAHs generated by burning smoky coals, has been considered as the most probable reason. The air pollution may affect drinking water and soil through dry and wet deposition. In this study, the concentrations of PAHs in water and soil samples from Xuanwei and Fuyuan were monitored to investigate the influence of atmospheric PAHs pollution on water and soil. No obvious PAHs pollution in water was found in these two areas, indicating that airborne PAHs have no apparent effect on the drinking water (well water). The smoky coal combustion from household and industry, such as the activities related to power plants, coking plants and chemical industries, is responsible for the soil PAHs pollution in these two areas. The soil pollution might be the reemission source and would pose long-term threat to the local environment and health of residents.
LU JunGangXU RenJiZHANG QingHuaLIU JiYanLIAO ChunYangWEI FuSheng
关键词:土壤污染PAHS
An analytical method for chlorinated paraffins and their determination in soil samples被引量:4
2010年
Short chain chlorinated paraffins (SCCPs) are possibly persistent organic pollutants (POPs), and are candidate POPs of the Stockholm Convention. In this study, three quantitative methods for analyzing CPs were compared using a gas chromatograph-electron capture detector (GC-ECD), gas chromatograph-electron capture negative ion low resolution mass spectrometry (GC-ECNI-LRMS) and gas chromatograph-electron ionization tandem mass spectrometry (GC-EI-MS2). A quantitative method for the analysis of total CPs in soil samples was established. The environmental levels of CPs in an e-waste dismantling area in China were evaluated.
YUAN Bo WANG YaWei FU JianJie ZHANG QingHua JIANG GuiBin
关键词:氯化石蜡土壤样品持久性有机污染物电子捕获检测器斯德哥尔摩公约串联质谱法
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