The approximately equimolar ratio AlCrNiSiTi multi-principal element alloy(MPEA) coatings were fabricated by laser cladding on Ti-6A1-4V(Ti64) alloy.Scanning electron microscopy(SEM),equipped with an energy-dispersive spectroscopy(EDS),and X-ray diffraction(XRD) were used to characterize the microstructure and composition.Investigations show that the coatings consist of(Ti,Cr)_5Si_3 and NiAl phases,formed by in situ reaction.The phase composition is initially explicated according to obtainable binary and ternary phase diagrams,and the formation Gibbs energy of Ti_5Si_3,V_5Si_3 and Cr_5Si_3.Dry sliding reciprocating friction and wear tests of the AlCrNiSiTi coating and Ti64 alloy substrate without coating were evaluated.A surface mapping profiler was used to evaluate the wear volume.The worn surface was characterized by SEM-EDS.The hardness and wear resistance of the AlCrNiSiTi coating are well compared with that of the basal material(Ti64).The main wear mechanism of the AlCrNiSiTi coating is slightly adhesive transfer from GCr15 counterpart,and a mixed layer composed of transferred materials and oxide is formed.
Can HuangYi-Zhou TangYong-Zhong ZhangAn-Ping DongJian TuLin-Jiang ChaiZhi-Ming Zhou
The interfacial reaction between aluminum melt and molten slag under an electric field plays a significant role in aluminum electro-slag refining. Here we studied this interfacial reaction within 680 and 820 ℃ under an electric field between 0 and 9 V. The evolution of aluminum composition was analyzed by inductively coupled plasma atomic emission spectroscopy. The dominant factor during the interfacial reaction was identified through orthogonal experiments, in which the slag-to-aluminum mass ratio, initial silicon concentration, electric voltage, reaction time, and temperature were selected as the influence factors. The greatest influence factor on the interfacial reaction was found to be the reaction time. Also,single-factor experiments revealed that the reaction kinetic processes largely obeyed an irreversible kinetic model, and the silicon removal efficiency was enhanced by increasing the voltage and slag/metal ratio.
