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国家自然科学基金(51006103)

作品数:7 被引量:37H指数:4
相关作者:朱建国吕清刚欧阳子区侯海盟王俊更多>>
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7 条 记 录,以下是 1-7
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无烟煤粉循环流化床预热过程中的煤氮转化特性被引量:1
2014年
在基于循环流化床预热的无烟煤粉燃烧实验台上,在循环流化床空气当量比低于0.3的条件下对无烟煤粉在预热过程中煤氮的迁移和转化特性进行了研究.结果表明,煤氮的主要转化产物为NH3和N2;随着煤中挥发分含量的升高和煤阶的降低,煤氮的转化率和煤氮向N2的转化率增加;随着预热温度的升高,煤氮的转化率和煤氮向N2的转化率增加,预热生成的NH3质量浓度降低;随着循环流化床空气当量比的增加,煤氮的转化率和煤氮向N2的转化率增加,预热生成的NH3的质量浓度降低.煤氮向NH3和N2的转化反应以及NH3和N2之间的转换反应是决定无烟煤预热过程中煤氮迁移转化的主要热化学反应.
欧阳子区朱建国吕清刚
关键词:无烟煤循环流化床NH3N2
煤气化与燃烧生成烟气中含氮化合物的测试方法被引量:4
2013年
在基于循环流化床预热的无烟煤粉燃烧系统中,对煤气化过程和燃烧过程产生的含N化合物(NO,NO2,NH3和HCN等)的分析方法进行了探讨。分别采用傅里叶变换红外光谱法、电化学法和化学溶液吸收法对烟气中的含N化合物进行分析。结果表明,循环流化床出口的气化烟气中含氮化合物应采用化学溶液吸收法进行分析,含氮化合物主要为NH3,测试值为881 mg/m3。利用傅里叶变换红外光谱法能够准确分析下行燃烧室燃烧烟气中含氮化合物。使用电化学法对NO进行分析时,装有硅胶颗粒的干燥筒对分析值有较大的影响。
欧阳子区朱建国矫维红吕清刚
关键词:煤气化燃烧分析方法含氮化合物
预热温度对无烟煤粉燃烧特性的影响被引量:8
2013年
在基于循环流化床预热的无烟煤粉燃烧试验台上,对阳泉无烟煤粉进行了预热燃烧试验,研究了不同预热温度下预热燃料的燃料特性、燃烧特性和NO_x排放特性,预热后燃料比表面积和总孔体积增大;预热燃料在下行燃烧室中燃烧稳定,轴向温度分布均匀,燃烧效率最高达94.1%;在预热温度为800℃、850℃、900℃和950℃的条件下,NO_x排放浓度分别为372 mg/m^3、295 mg/m^3、259 mg/m^3和265 mg/m^3,较无烟煤粉的常规燃烧方式明显降低.
欧阳子区朱建国吕清刚侯海盟
关键词:循环流化床预热燃料特性燃烧特性氮氧化物
天然气燃烧特性与NO_x排放特性数学模拟被引量:1
2013年
采用详细化学反应机理并运用良好搅拌反应器模型,通过化学反应动力学模型的数值计算,就典型的4种天然气组分进行了多种工况下的燃烧特性与NOx排放特性研究。计算结果表明:助燃剂中氧含量对着火时间非常敏感,氧含量较高,着火时间提前;低氧和富燃燃烧方式均可减少NOx排放。
黄毅朱建国
关键词:天然气燃烧特性NOX排放特性数学模拟
循环流化床预热的无烟煤粉燃烧特性试验研究被引量:7
2011年
采用基于将煤粉在CFB(循环流化床)低空气当量比下部分燃烧,使其预热到800℃以上再进行燃烧的新工艺,研究无烟煤煤粉的稳燃特性。为此,搭建了基于CFB(循环流化床)预热的无烟煤燃烧系统,其中CFB(循环流化床)提升管直径90mm,高度1 500mm;下行燃烧室直径260mm,高度3 000mm。用挥发分含量为6.67%的无烟煤粉为燃料的试验表明:在CFB(循环流化床)空气当量比低于0.3条件下,可持续稳定的将无烟煤粉预热到800℃以上;煤粉经预热后粒径显著减小,比表面积、总孔体积显著增大;高温预热煤粉在下行燃烧室内燃烧迅速、并在1 100℃温度下能够稳定燃烧,燃烧效率达到91.46%。
吕清刚王俊朱建国
关键词:循环流化床预热无烟煤粉燃烧特性
Numerical Simulation on Pulverized Coal Combustion and NO_x Emissions in High Temperature Air from Circulating Fluidized Bed被引量:8
2013年
High temperature air combustion is a prospecting technology in energy saving and pollutants reduction. Numerical simulation on pulverized coal combustion and NOx emissions in high temperature air from circulating fluidized bed was presented. The down-fired combustor, taken as the calculation domain, has the diameter of 220 mm and the height of 3000 mm. 2 cases with air staging combustion are simulated. Compared the simulation results with experimental data, there is a good agreement. It is found that the combustion model and NOx formation model are applicable to simulate the pulverized coal combustion and NOx emissions in high temperature air from circulating fluidized bed. The results show that there is a uniform temperature profile along the axis of the down-fired combustor. The NOx emissions are lower than those of ordinary pulverized coal combustion, and the NOx emissions are 390 mg/m3 and 352 mg/m3 in Case 1 and Case 2, respectively. At the range of 300-600 mm below the nozzle, the NO concentration decreases, mainly resulting from some homogeneous reactions and heterogeneous reaction. NO concentration has a little increase at the position of 800 mm below the nozzle as the tertiary air supplied to the combustor at the position of 600 mm below the nozzle.
Jianguo ZhuZiqu OuyangQinggang Lu
关键词:COALCOMBUSTIONNUMERICALAIR
Experimental Study on Combustion Characteristics and NOX Emissions of Pulverized Anthracite Preheated by Circulating Fluidized Bed被引量:18
2011年
A 30 kW bench-scale rig of pulverized anthracite combustion preheated by a circulating fluidized bed (CFB) was developed. The CFB riser has a diameter of 90 mm and a height of 1,500 mm. The down-fired combustion chamber (DFCC) has a diameter of 260 mm and a height of 3,000 mm. Combustion experiments were carded out using pulverized anthracite with 6.74% volatile content. This low volatile coal is difficult to ignite and burn out. Therefore, it requires longer burnout time and higher combustion temperature, which results in larger NOx emis- sions. In the current study, important factors that influence the combustion characteristics and NOx emissions were investigated such as excess air ratio, air ratio in the reducing zone, and fuel residence time in the reducing zone. Pulverized anthracite can be quickly preheated up to 800~C in CFB when the primary air is 24% of theo- retical air for combustion, and the temperature profile is uniform in DFCC. The combustion efficiency is 94.2%, which is competitive with other anthracite combustion technologies. When the excess air ratio ranges from 1.26 to 1.67, the coal-N conversion ratio is less than 32% and the NOx emission concentration is less than 371 mg/m^3 (@6% O2). When the air ratio in the reducing zone is 0.12, the NOx concentration is 221 mg/m^3 (@6% O2), and the coal-N conversion ratio is 21%, which is much lower than that of other boilers.
WANG JunZHU Jian-guoLU Qing-gang
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