＜正＞There is growing interest in the active site structure and catalytic function of metal containing metallopr...
Zhiquan Pan, Hong Zhou, Zhenghe Peng, Hanping Zhang School of Chemical Engineering and Pharmacy, Wuhan Institute of Chemical Technology, Wuhan, 430073 College of Chemistry and Molecular Science, Wuhan University, Wuhan 430072
＜正＞It is well known that polyamines are very excellent complex agents for transition metal ions. The metal pol...
Hong Zhou, Zheng-He Peng, Zhi-Quan Pan School of Chemical Engineering and pharmacy of Wuhan Institute of Chemical Technology, Wuhan 430073 College of Chemistry and Molecular Science of Wuhan University, Wuhan 430072
大环双核铜(Ⅱ)配合物由N,N′-二甲基-N,N′-二(3-甲酰基-5-氯水杨醛)乙二胺和1,3-丙二胺,与铜(Ⅱ)反应形成的,经过X-射线单晶衍射结果表明:a=0.87105(16)nm,b=0.95778(18)nm,c=1.8104(3)nm,β=100.761(18)°,V=1.4838(5)nm3,Z=2,Dc=1.762Mg.m-3,μ=1.85 mm-1,F(000)=796,and final R1=0.061,wR2=0.126。晶体结构表明:两个铜离子位于双核大环中间,与大环的胺、亚胺以及酚羟基的氧进行配位。磁性结果表明配合物为反铁磁性。
