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福建省自然科学基金(2013J05027)

作品数:6 被引量:13H指数:2
相关作者:俞瀚黄清明俞建长张新奇曹文兵更多>>
相关机构:福州大学更多>>
发文基金:福建省自然科学基金国家自然科学基金更多>>
相关领域:化学工程理学一般工业技术环境科学与工程更多>>

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6 条 记 录,以下是 1-6
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Pt/FeSnO(OH)_5: A Novel Supported Pt Catalyst for Catalytic Oxidation of Benzene
2016年
Pt/FeSnO(OH)_5 was synthesized as a novel catalyst for VOCs oxidation. Compared with Pt/γ-Al_2O_3 during catalytic oxidation of benzene, Pt/Fe Sn O(OH)5 showed better catalytic activity. After characterization of the catalysts by XRD, SEM, TEM, EDS, XPS, BET, TGA and DTA, we found most Pt could be reduced to metallic state when the hydroxyl catalyst was used as supporter, and the metallic Pt in Pt/Fe Sn O(OH)5 was more active than the oxidized Pt in Pt/γ-Al_2O_3 in catalytic oxidation of VOCs. Pt/FeSnO(OH)_5 shows both good catalytic activity and high stability, which may be a promising catalyst. This study may also be helpful for the design and fabrication of new catalysts.
俞瀚曹周明魏笑峰于岩
In^(3+)共掺杂诱导NaY_(0.95-x)Yb_(0.03)Er_(0.02)F_4相转变与上转换发光增强研究被引量:1
2013年
引入In3+作为新的掺杂离子通过水热法合成了In3+与Er3+,Yb3+共掺杂的NaYF4上转换发光材料.通过XRD表征及Rietveld精修,SEM以及TEM研究了In掺杂引起的NaYF4形貌与晶体结构的变化.通过发射光谱与发光衰减曲线表征了掺杂NaYF4的上转换发光性能,以研究晶体微观结构与上转换发光性能之间的关系.结果表明随着In掺杂量的增加,立方相NaYF4的晶格畸变不断增强且发生由立方相向六方相的转变.对于六方相NaYF4,其上转换发光强度随着In含量的提高不断增强并当In含量为3%时达到最大值.该研究结果可以有助于设计与合成具有优良上转换发光性能的材料.
俞瀚黄清明曹文兵张新奇俞建长
关键词:掺杂相转变
Double Hydrothermal Synthesis of Graphene Supported TiO_2(b)Nanosheets as Anode Materials for Lithium Ion Batteries
2013年
The synthesis of graphene supported TiO2(b) nanosheets by a double hydrother- mal method for lithium storage was reported. The titanate nanosheets synthesized by the first hydrothermal progress and the graphene oxide obtained by the oxidation of graphite were hydrothermally treated together to fabricate the TiO2(b)/graphene composite. The electrochemical measurements illustrate that the graphene supporter obviously improves the cyclic performance of TiO2(b), which can be attributed to the better dispersion and the decrease of resistance for the TiO2(b) nanosheets in the composite.
俞瀚孔景赖日裕
关键词:GRAPHENE
Synthesis of TiO_2/ZnSn(OH)_6 Hollow Nano-composite via a Simultaneous Crystallization-etching Route as Photocatalyst被引量:2
2013年
We report the synthesis of TiO2/ZnSn(OH)6 as a novel nano-composite material via a simultaneous crystallization-etching route with cubic nano-ZnSn(OH)6 and TiF4 as the precursors. The structure, composition and morphology of the composite were characterized by XRD, EDS, FETEM and FESEM, which showed the prepared TiO2/ZnSn(OH)6 had a unique morphology of hollow cubic nano-ZnSn(OH)6 attached with rutile TiO2 nanoparticles. The results of photocatalytic activity measurement indicated the photocatalytic activity of the prepared composite was better than that of nano-ZnSn(OH)6. This study may be helpful for the design and fabrication of functional comoosite materials.
YU HanLI Chang-RongCAO Zhou-MingZHANG Zi-Zhong
关键词:NANO-COMPOSITEPHOTOCATALYSIS
Eu^(3+)/Tb^(3+)/MoO_4^(2–)掺杂钨酸钙体系荧光粉的结构及其发光性能被引量:7
2015年
采用化学共沉淀法合成了Ca0.75Mg0.2Tb0.02Eu0.03(WO4)1-x(Mo O4)x(x=0~1.0)系列荧光粉,并对荧光粉的晶体结构和发光性能进行了表征。结果表明:不同Mo O42–掺杂量的样品均为四方相Ca0.75Mg0.2Tb0.02Eu0.03(WO4)1-x(Mo O4)x固溶体。在273 nm波长紫外光激发下,随着x的增大,Eu3+离子的发光强度先增强后减弱,当x=0.6时发光强度最强,为未掺杂Mo O42–样品的6倍。Mo O42–共掺杂改变了稀土离子周围的配位环境和局部晶体场的对称性,促进Eu3+离子4f电子的超敏跃迁,提高Eu3+的O2–→Eu3+电荷迁移跃迁,增加基体、Tb3+离子与Eu3+离子之间的能量传递。
杨成钢黄清明林清桂俞瀚俞建长
关键词:化学共沉淀法发光性能
Hf^(4+)共掺NaYF_4:Yb/Tm提高上转换发光性能研究被引量:3
2016年
利用X射线多晶衍射仪、场发射扫描电镜、场发射透射电镜、X射线光电子能谱和荧光光谱仪对相近半径离子Hf^(4+)和Zr^(4+)共掺六方Na YF_4:Yb^(3+)/Tm^(3+)的结构、形貌和上转换发光性能进行研究.结果表明Hf^(4+)和Zr^(4+)离子共掺六方Na YF_4:Yb^(3+)/Tm^(3+)可有效调控晶场的不对称性,Hf^(4+)相对于Zr^(4+)是个更好的掺杂离子,它在调控晶场的同时还参与Tm^(3+)离子上转换发光的能量传递过程,明显提高了短波500 nm以下发射带的荧光强度;而Zr4+离子仅扮演晶场调控角色而未能参与稀土离子Tm^(3+)的上转换发光过程,Tm^(3+)离子小于500 nm短波发射带的荧光强度没有得到明显的提高,仅提高802 nm发射带的荧光强度.该研究发现Hf^(4+)可作为蓄能离子参与稀土离子的上转换发光过程,有助于将Hf^(4+)作为蓄能离子和晶格操纵工具用于设计和制备其它高性能的稀土上转换发光材料.
黄清明俞瀚张新奇曹文兵俞建长
关键词:晶体场
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