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国家自然科学基金(30870311)

作品数:4 被引量:81H指数:4
相关作者:戴家银曹宏许木启胡国成麦碧娴更多>>
相关机构:中国科学院河北大学中华人民共和国环境保护部更多>>
发文基金:国家自然科学基金国家重点基础研究发展计划更多>>
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Organochlorine compounds and polycyclic aromatic hydrocarbons in surface sediment from Baiyangdian Lake,North China:Concentrations,sources profiles and potential risk被引量:43
2010年
Organochlorine pesticides (OCPs), polychlorinated biphenyls (PCBs), and polycyclic aromatic hydrocarbons (PAHs) were determined in nineteen surface sediment samples collected from Baiyangdian Lake and its inflowing river (Fuhe River) in North China. Total concentrations of OCPs, PCBs and PAHs in sediments ranged from 5.4 to 707.6 ng]g, 2.3 to 197.8 ng/g, and 101.3 to 6360.5 ng]g, respectively. The levels of contaminants in Fuhe River were significantly higher than those in Baiyandian Lake. For hexachlorocyclohexane (HCHs) and dichlorodiphenytrich/oroethanes (DDTs), α-HCH and p,p'-DDT were predominant isomers; while for PCBs, PCB 28/31, PCB 40/103, PCB 60, PCB 101, and PCB 118 were predominant congeners. Possible sources derived from historical usage for OCPs and incomplete combustion fuel, wood, and coal and exhaustion of boats or cars for PAHs. Risk assessment of sediment indicated that sediments in Fuhe River were likely to pose potential biological adverse impact.
Guocheng HuXiaojun LuoFengchao LiJiayin DaiJianyang GuoShejun ChenCao HongBixian MaiMuqi Xu
关键词:CONCENTRATIONS
Distribution of polybrominated diphenyl ethers and decabromodiphenylethane in surface sediments from Fuhe River and Baiyangdian Lake,North China被引量:19
2010年
Nineteen surface sediment samples collected from Baiyangdian Lake and its inflowing river (Fuhe River) in North China were analyzed for polybrominated diphenyl ethers (PBDEs) and decabromodiphenylethane (DBDPE). The concentrations of PBDEs and DBDPE in sediments ranged from 5.5 to 300.7 ng/g dry weight (dw) and 1.1 to 68.2 ng/g dw, respectively. Their levels in sediments in Fuhe River were significantly higher than those in Balyandian Lake. Compared to data from other regions, the PBDE levels in surface sediments from Baiyangdian Lake and Fuhe River were in the medium to lower range. Among the PBDE congeners, BDE209 was predominant, with contributions to the total PBDEs ranging from 79.4% to 97.3% in sediment samples. For the lowly brominated congeners (tri- to hepta-BDE), BDE47 and BDE99 were the most abundant, which contributed 52.1% and 44.1% to the sum of tri- to hepta-BDEs in the sediments from Baiyangdian Lake and Fuhe River, respectively. The compositional patterns of PBDEs in Baiyangdian Lake sediments indicated that technical deca-BDE mixture was the major pollutant sources with a minor contribution of penta-BDE mixture. The present study suggested that the importance of Fuhe River as a possibly potential sources of PBDEs contamination in Baiyangdian Lake.
Guocheng HuZhencheng XuJiayin DaiBixian MaiHong CaoJianshe WangZhimin ShiMuqi Xu
关键词:CONTAMINATION
有机氯农药和多溴联苯醚在白洋淀鸭子组织中分布特征研究被引量:10
2010年
利用气相色谱-质谱(GC/MS)方法定量分析了白洋淀鸭子肌肉、肝脏、脑组织中HCHs、DDTs和PBDEs的分布特征.结果表明,3种组织中HCHs和DDTs的含量范围分别为0.9~5.0 ng/g(以湿重计,下同)和0.3~2.8 ng/g,而PBDEs的含量范围是0.03~0.65 ng/g.统计分析鸭子不同组织中持久性卤代烃的含量差异,结果显示,DDTs和PBDEs的含量水平有较大差异(p<0.05);而HCHs在3种组织中的含量差异不明显(p>0.05).肝脏中DDTs和PBDEs的平均含量较高,分别为2.3和0.37 ng/g.在HCHs和DDTs同系物(代谢物)组成中,β-HCH在肝脏和脑组织中占主要地位,p,p′-DDE是DDTs的主要代谢产物;在PBDEs同系物中,BDE47和BDE99是鸭子组织中主要的组成部分.鸭子不同组织中HCHs、DDTs和PBDEs的组成模式反映了白洋淀仍然受到历史残留的有机氯农药污染;同时,来自白洋淀上游的工业污染很可能输入新型持久性有机污染物(PBDEs).
胡国成许振成戴家银许木启麦碧娴曹宏王建设石志敏
关键词:有机氯农药多溴联苯醚鸭子
府河和白洋淀沉积物中DDTs的分布特征和风险评估被引量:11
2009年
利用气相色谱-质谱(GC-MS)检测了府河和白洋淀共计19个表层沉积物样品中的W(DDTs)及其分布特征.结果表明,W(DDTs)为1.74~51.33ng/g(以干质量计),平均值为11.01ng/g,其分布特征呈现从府河到白洋淀逐渐递减的趋势.与国内其他地区沉积物相比,府河和白洋淀地区DDTs的污染处于中等偏低的水平.在所有沉积物样品中,P,P′-DDT所占比例较大,是最主要的异构体.大部分样品中W(DDD)/w(DDE)大于1,而W(DDT)/W(DDE+DDD)小于1,说明研究区DDT处于厌氧环境条件,且没有新的DDT输入.该地区DDTs主要来源于农田土壤侵蚀及工业废水排放.潜在风险评估表明,府河和白洋淀的表层沉积物中DDTs对周围环境具有一定的影响,应引起相关部门的重视.
胡国成李凤超戴家银罗孝俊麦碧娴陈社军曹宏许木启
关键词:风险评估沉积物
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