The FeCl3-catalyzed aerobic oxidation process for the synthesis of benzoxazoles,benzothiazole and benzimidazole has been discovered.This method has proved to be effective to a wide range of substrates,and it has been applied for the synthesis of JTP-426467.
CAO Ke,TU YongQiang & ZHANG FuMin P State Key Laboratory of Applied Organic Chemistry and Department of Chemistry,Lanzhou University,Lanzhou 730000,China
Construction of the polyaryl quaternary unit through a ZnBr2 catalyzed tandem coupling/semipinacol rearrangement participated by allylic cations was reported for the first time.
YUAN DaoYi,ZHANG YongQiang,TU YongQiang,CHEN ZhiHua & ZHAO Xiong State Key Laboratory of Applied Organic Chemistry
