High resolution solid-state 29Si MAS NMR,combined with XRD,SEM and FTIR were used to characterize the pozzolanic activity of FA,type of main pozzolanic reaction products,and the effect of pozzolanic reaction on the C-S-H microstructure in fly ash-cement (FC) paste.The experimental results indicate that in the hydrated FC paste with 30% dosage of FA at 3 d,FA partially participated in the pozzolanic reaction,while,at 120 d,FA largely reacts.During the hydration of FC paste at laboratory temperature,the pozzolanic reaction products are C-S-H gel rather than zeolitic gel.Moreover,after the covalent bonds of Si-O-Si,Si-O-Al and Al-O-Al in the structure of FA are broken,monosilicates Si-OH and Al-OH groups form,these chemical species can connect C-S-H dimers,thus producing more Al-free C-S-H and aluminous C-S-H than in the plain cement paste.The increased content of Al for Si substitution in the bridging tetrahedra of C-S-H may decrease the stability of C-S-H,which results in a rather obvious loss in the mechanical strength of hardened FC paste.
Sol-gel method is a technique to synthesize inorganic materials based on wet-chemical reaction theory. The results have shown that reactants tetraethyl orthosilicate (TEOS) and Ca(NO3)2·4H2O can form sol and gel in solution at 50-60 ℃, and the cosolvents are propyl alcohol (NPA) and H2O, the catalyst is HNO3. This sol-gel is burned for 12 hat 1 350-1 450 ℃ so that the organic matter, free water (moisture) in sol-gel system are removed and a solid reaction has taken place to form the resulting product. The product has been confirmed to be C3S by XRD, SEM and 29Si MAS NMR, as well as free lime content of the product which is less than 0.2% was determined by propanetriol-ethanol-method. The analysis determined by EDXA has indicated that the n(Ca)/n(Si) ratio in corresponding to micro-region is close to theoretical value of 3∶1. This resulting product is C3S with Si sites of Q0 polymerization, and has higher purity and hydraulic activities at earlier age of hydration.
In this paper, we investigates the concretes respectively incorporated with 5%(m︰m) nano-SiO2(NS), 40%(m︰m) super- fine slag(SS), as well as 40%(m︰m) SS combining 20% replacement of sand volume with RP. The tested mechanical properties include compressive strength, abrasion resistant strength, and elastic modulus. The results indicate that among these concretes, the SS-RP concrete has the highest abrasion resistant strength with increment ratios of 1.71 and 1.35 at 28 days and 90 days, respectively; the SS concrete has the highest compressive strength with increment ratios of 2.03 and 1.95 at 28 days and 90 days, respectively; the elastic modulus of SS-RP concrete significantly decrease compared with the SS concrete and is slightly higher than that of the reference concrete. It is concluded that NS, SS, and RP all can improve the abrasion resistance of concrete, and it will be significantly improved when SS combining RP is incorporated.
