[Objective] A heavy rainstorm in Jincheng in August in 2010 was expounded. [Method] By dint of the conventional meteorological data, and automatic weather station data, and Doppler radar data, one severe torrential rainstorm was analyzed from the aspect of circulation background, physical quantity field, satellite cloud image, and radar echo, etc. [Result] The rainstorm was in the circulation field of low-west-east-obstruction, and was formed under the middle and low layer shear line and low air torrent situation. The low layer shear and convergence of wind favorable to the lift of unsteady air around Jincheng. The intrusion of cold air in the low layer of convective layer and above the ground trigered such convective weather. The torrent of the low air in the southwest sent abundant water vapor to the rainstorm area. The high temperature and the moisture accumulated much unsteady energy for the generation of rainstorm. The main precipitation system of this process was the singular of convective echo which was stimulated by the ground mesoscale shear line. Under the guidance of southwest airstream of the low and middle air, the convective echo singular formed train effect by moving towards Jincheng and formed large rainstorm. Doppler radar data suggested that the characteristics of the generation, development and movement of this mesoscale rainstorm system. The strong precipitation center was in the large value area of the gradient in the back of the TBB center. [Conclusion] The study provided references for the forecast and pre-warning of temporary rainstorm of such kind.
The reaction mechanism of ozone （O 3） addition to the double bonds of gas phase keto-limonene was investigated using ab initio methods.Two different possibilities for O 3 addition to the double bond were considered and two corresponding van der Waals complexes （Complex 1 and Complex 2） were found for 1-endo and 2-endo.The rate constants were calculated using the transition state theory at the CCSD（T）/6-31G（d）＋ CF//B3LYP/6-31G（d,p） level.The high-pressure limit of the total rate constant at 298 K was 3.51×10-16 cm 3/（molecule·sec）,which was in a good agreement with the experimental data.
