A recyclable fluorescence sensor for Hg2+ and Zn2+, based on rhodamine 6G(R6G) and 8-aminoquinoline(8-AQ) co-modified core/shell Fe3O4@Si O2 nanoparticles(denoted as R6G/8-AQ co-functionalized Fe3O4@Si O2 NPs), was developed. R6 G derivative and 8-AQ derivative were conjugated onto the water-soluble core/shell Fe3O4@Si O2 nanoparticles(NPs) by covalent interaction. The R6G/8-AQ co-functionalized core/shell Fe3O4@Si O2 NPs showed fluorescence emission bands at 548 and 480 nm. When the R6G/8-AQ co-functionalized core/shell Fe3O4@Si O2 NPs were coordinated with Hg2+ and Zn2+, emission intensity at 548 nm increased with [Hg2+], while that at 480 nm increased with [Zn2+]. Moreover, there existed approximate linear relationships between fluorescence intensities and concentration of metal ions, in the range of 4.0×10-9–7.65×10-8 M for Hg2+ and 3.3×10-9–3.96×10-8 M for Zn2+, respectively. The lower detection limits for Hg2+ and Zn2+ were 1.0×10-9 and 3.0×10-9 M, respectively. The R6G/8-AQ co-functionalized core/shell Fe3O4@Si O2 NPs showed good selectivity to Hg2+ and Zn2+ over other common metal ions examined in neutral aqueous solutions. Moreover, the R6G/8-AQ co-functionalized core/shell Fe3O4@Si O2 NPs could be recycled from the detected samples using a magnet. This work has thus showed not only a practical sensing method for Zn2+ and Hg2+, but also a promising guide to the design of fluorimetric/colorimetric sensors for other targets.
提出了一种He气辅助熔接的全光纤型空芯光子晶体光纤(HC-PCF)低压气体腔的制备方法。通过用高压待充气体冲洗HC-PCF,确保了腔内的气体纯度;通过利用光谱监测系统监测HC-PCF降压过程及He气辅助熔接过程中CO2吸收光谱的变化,研究了HC-PCF中气体动力学运动过程;通过利用He气辅助熔接方法,制备得到压强为7 k Pa、插入损耗小于2 d B、长度为10 m的全光纤型HC-PCF低压CO2气体腔。该方法也适用于更低压强的HC-PCF气体腔的研制,且制备的气体腔具有良好的气密性和长期稳定性。
实验研究了激光诱导化学沉积法(LICDM)中诱导激光功率及诱导时间对锥形光纤表面增强拉曼散射(SERS)探针性能的影响。通过优化激光诱导功率为90 m W、诱导时间为50 min,制备出高灵敏度的锥形光纤SERS探针,结合便携式拉曼光谱仪实现了1.0×10-7mol/L甲基对硫磷(MP)的检测;该方法制备的探针对MP的SERS光谱检测具有良好的重复性。这种高灵敏度、可重复性好的锥形光纤SERS探针在农残现场检测、定量分析等方面具有潜在的应用前景。
A compact and stable all-normal-dispersion mode-locked ring fiber laser with the repetition rate of 312 MHz is obtained with a wavelength-division multiplexing isolator. The compressed pulse is nearly transform-limited and the pulse width is 118 fs. It exhibits an optical efficiency of 50% and the maximum output power is about 205 mW with a 410 mW pump.
The surface topography of noble metal particles is a significant factor in tailoring surface-enhanced Raman scattering （SERS） properties. Here, we present a simple fabrication route to hexagonally arranged arrays of surface-roughened urchin- like Ag hemispheres （Ag-HSs） decorated with Ag nanoparticles （Ag-NPs） for highly active and reproducible SERS substrates. The urchin-like Ag-HS arrays are achieved by sputtering Ag onto the top surface of a highly ordered porous anodic aluminum oxide （AAO） template to form ordered arrays of smooth Ag-HSs and then by electrodepositing Ag-NPs onto the surface of each Ag-HS. Owing to the ordered arrangement of the Ag-HSs and the improved surface roughness, the urchin-like hierarchical Ag-HS arrays can provide sufficient and uniform ＂hot spots＂ for reproducible and highly active SERS effects. Using the urchin-like Ag-HS arrays as SERS substrates, 10-7 M dibutyl phthalate （a member of plasticizers family） and 1.5 × 10-5 M PCB-77 （one congener of polychlorinated biphenyl, a notorious class of pollutants） are identified, showing promising potential for these substrates in the rapid recognition of organic pollutants.
Haibin TangGuowen MengZhongbo LiChuhong ZhuZhulin HuangZhaoming WangFadi Li
A facile synthetic approach has been developed to prepare uniform and size-tunable spiky Au@Ag core-shell nan oparticles (NPs) to tailor the localized surface plasm on res onance (LSPR) properties. The gradual assembly of small Au nano crystals allows the size of spiky Au NPs to be modulated from tens to several hundreds of nano meters by tuning the concentration of initial Au seeds and Au source;and the thick ness of the Ag shell can be adjusted with stepwise reduction of Ag(l)ions. The LSPR bands of such spiky Au@Ag core-shell NPs resemble those of pure spiky Au NP cores of similar sizes in near-infrared region, and increasing the Ag shell thickness results in a blue shift and broadening of the LSPR band in the n ear-i nfrared regi on. Additi on ally, the spiky Au@Ag core-shell NPs exhibit improved surface-e nhan ced Rama n scattering (SERS) activity as compared to the bare spiky Au NPs and spherical Ag@Au NPs. This work has offered a facile route to synthesize plasmonic metal NPs with LSPR band in 650 to 800 nm that show strong enhancement of localized electromagnetic field, which provides an effective SERS substrate for SERS imaging and detection in biological fluids and tissues.
