Real-time laser holographic interferometry was applied to measure liquid concentrations of CO2 in the vicinity of gas-liquid free interface under the conditions of cocurrent gas-liquid flow for absorption of CO2 by ethanol. The influences of the Reynolds number on the measurable interface concentration and on the film thickness were discussed. The results show that CO2 concentration decreases exponentially along the mass transfer direction,and the concentration gradient increases as Reynolds number of either liquid or gas increases. CO2 concentrations fluctuate slightly along the direction of flow; on the whole, there is an increase in CO2 concentration. The investigation also demonstrated that film thickness decreases with the increase of Reynolds number of either of the two phases. Sherwood number representing the mass transfer coefficient was finally correlated as a function of the hydrodynamic parameters and the physical properties.
Real-time laser holographic interferometry was applied to measure liquid concentrations of CO2 in the vicinity of gas-liquid free interface under the conditions of cocurrent gas-liquid flow for absorption of CO2 by ethanol. The influences of the Reynolds number on the measurable interface concentration and on the film thickness were discussed. The results show that CO2 concentration decreases exponentially along the mass transfer direction, and the concentration gradient increases as Reynolds number of either liquid or gas increases. CO2 concentrations fluctuate slightly along the direction of flow; on the whole, there is an increase in CO2 concentration. The investiga- tion also demonstrated that film thickness decreases with the increase of Reynolds number of either of the two phases. Sherwood number representing the mass transfer coefficient was finally correlated as a function of the hy- drodynamic parameters and the physical properties.
It has long been found that the flow pattern of the liquid phase on distillation tray is of great importance on distillation process performance. But until now, there was very few published work on quantitative investigation of this subject. By combining the computational fluid dynamics (CFD) with the mass transfer equation, a theoretical model is proposed for predicting the details of velocity and concentration distributions as well as the tray efficiency of distillation tray column. Using the proposed model, four different cases corresponding to different assumptions of liquid and vapor flowing condition for a distillation tray column were investigated. In Case I, the distributions of velocity and concentration of the incoming liquid from the downcomer and the uprising vapor from the underneath tray spacing are uniform. In Case Ⅱ, the distribution of the incoming liquid is non-uniform but the uprising vapor is uniform. In Case Ⅲ, the distribution of the incoming liquid is uniform but the uprising vapor is non-uniform.In Case IV, the distributions of both the incoming liquid and the uprising vapor are non-uniform. The details of velocity and concentration distributions on a multiple sieve tray distillation column in four different cases were simulated using the proposed model. It is found that the shape of the simulated concentration profiles of vapor and the liquid is quite different from case to case. The computed results also show that the tray efficiency is highly reduced by the maldistribution of velocity and concentration of the incoming liquid and uprising vapor. The tray efficiency for Case Ⅰ is higher than Case Ⅱ or Case Ⅲ, and that for Case Ⅳis the lowest. It also reveals that the accumulated effect of maldistribution becomes more pronounced when the number of column trays increased. The present study demonstrates that the use of computational method to predict the mass transfer efficiency for the tray column, especially for the large one, is feasible.
