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国家自然科学基金(21003094)

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发文基金:国家教育部博士点基金国家自然科学基金更多>>
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Simulated-sunlight-activated photocatalysis of Methylene Blue using cerium-doped SiO_2/TiO_2 nanostructured fibers被引量:10
2012年
Cerium-doped SiO 2 /TiO 2 nanostructured fibers were fabricated by electrospinning technology.The prepared fibers were characterized by thermogravimetric analysis(TGA),scanning electron microscopy(SEM),X-ray diffraction(XRD) and Fourier transform infrared spectroscopy(FT-IR).Using the fibers as catalysts,photocatalytic degradation of Methylene Blue(MB) aqueous solution was carried out under simulated sunlight.The 0.2% Ce doping proved to be the optimal concentration for the doping of TiO 2 /SiO 2,compared to other Ce-doped molar concentrations.The 0.2% Ce-doped SiO 2 /TiO 2 fibers exhibited higher photocatalytic activity than industrial Degussa P25 and the samples doped with only Ce or SiO 2.The reasons for improving the photocatalytic activity were also discussed.Several operational parameters were studied,which showed that the photocatalytic efficiency of MB was influenced by parameters such as the initial dye concentration,the initial pH,inorganic anions,and so on.In addition,the influences of an electron acceptor and a radical scavenger suggested that OH was the dominant photooxidant during the photocatalytic process.The reuse evaluation of the fibers indicated that their photocatalytic activity had good stability.
Yu LiuHongbing YuZhenning LvSihui ZhanJiangyao YangXinhong PengYixuan RenXiaoyan Wu
关键词:TIO2/SIO2傅里叶变换红外光谱
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