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国家自然科学基金(20821062)

作品数:4 被引量:1H指数:1
相关作者:王剑波莫凡洋李飞更多>>
相关机构:北京大学更多>>
发文基金:国家自然科学基金国家重点基础研究发展计划更多>>
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钯卡宾为基础的催化反应研究
<正>金属卡宾是含有碳金属双键的一类结构,是许多重要催化反应的中间体,其最典型的反应有环丙烷化、生成叶立德以及X-H键插入(X=C,Si,N,O等)。另一方面,钯络合物是金属有机反应中应用最为广泛的一类催化剂,特别是各类...
王剑波
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(±)Schindilactone A的立体选择性全合成
Schindilactone A是由昆明植物所孙汉董院士与2007年从五味子中提取分离出来。该类天然产物具有抗肿瘤和抗病毒的活性.鉴于该类分子的生物活性以及结构新颖性和合成的挑战性,许多课题组开展了该类天然产物的合成研究...
任为武肖青孙天文李勇许灵敏单振华唐叶峰陈家华杨震
关键词:全合成
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New Strategy to Construct Fused/Bridged/Spiro Carbocyclic Scaffolds Based on the Design of Novel 6-C Synthon Precursor
<正>Fused/bridged/spiro carbocyclic ring scaffolds are one of most important motifs in natural and synthetic or...
Jia Liu,~(1,2) Xi Wang,~1 Chang-Liang Sun,~1 Bi-Jie Li,~1 Min Wang,~2 Zhang-Jie Shi~(*1,3) 1 Beijing National Laboratory of Molecular Sciences(BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education,College of Chemistry and Molecular Engineering and Green Chemistry Center,Peking University,Beijing 100871 and Department of Chemistry,2 University of Agriculture of China,Beijing 100094 and 3 State Key laboratory of Organometallic Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China
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LiCl-Promoted Pd(Ⅱ)-Catalyzed ortho Carbonylation of N,N-Dimethylbenzylamines
<正>Palladium-catalyzed highly regioselective carbonylation of substituted N,N-dimethylbenzylamines was develop...
Hu Li,~1 Gui-Xin Cai,~1 Zhang-Jie Shi~(*1,2) 1 Beijing National Laboratory of Molecular Sciences(BNLMS),PKU Green Chemistry Center and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education,College of Chemistry, Peking University,Beijing 100871,China 2 State Key Laboratory of Organometallic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China
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Pd-Catalyzed Three-Component Coupling of N-Tosylhydrazone,Terminal Alkyne and Aryl Halide
<正>The transition metal catalyzed reactions of diazo compounds have been well-established as powerful approach...
Lei Zhou,Fei Ye,Yan Zhang and Jianbo Wang~* Beijing National Laboratory for Molecular Sciences(BNLMS),Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education,College of Chemistry,Peking University,Beijing 100871,China
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γ-取代的α-重氮β-羰基酯化合物的烯醇锂盐对N-亚磺酰亚胺的高度非对映选择性加成
2010年
α-重氮β-羰基酯衍生物是一类重要的多官能团分子构件,对这类化合物进行衍生化可以得到很多在生物、制药或材料等领域里有重要应用价值的分子.
莫凡洋李飞王剑波
关键词:羰基重氮酰亚胺锂盐烯醇
Fe-Catalyzed Cross-Coupling of Aryl and Vinyl Carboxylates with Grignard Reagents under Mild Conditions
<正>Previously,we have reported the nickel-catalyzed cross-coupling of aryl carboxylates with aryl boron and ar...
Bi-Jie Li,Li Xu,and Zhang-Jie Shi~* Beijing National Laboratory of Molecular Sciences(BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education,College of Chemistry and Green Chemistry Center,Peking University,Beijing 100080,China
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Construction of Polysubstituted Olefins through Ni-Catalyzed Direct Activation of Alkenyl C-O of Substituted Alkenyl Acetates
<正>We have first developed a Suzuki-Miyaura cross-coupling reaction between vinyl acetates and aryl boroxines ...
Chang-Liang Sun and Zhang-Jie Shi~* College of Chemistry and Molecular Engineering,Peking University,Beijing,100871
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Catalyst-Free Imidation of Allyl Sulfides with Chloramine-T and Subsequent [2,3]-Sigmatropic Rearrangement
2012年
江玉波莫凡洋邱迪匡春香张艳王剑波
关键词:胺化催化剂氯胺磺胺类药物
铜卡宾参与的偶联反应研究
<正>金属卡宾反应和过渡金属催化的交叉偶联反应是有机化学研究领域中两个十分重要的方向,相关的研究分别于2005年和2010年被授予诺贝尔化学奖。本课题组在基于金属卡宾为基础的催化反应方面有长年的工作积累。自2007年以来...
王剑波
关键词:交叉偶联催化重氮化合物
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