The eutectic CoFeNi2V0.5Nb0.75 high entropy alloys (HEAs) were heated at 500, 600, 700, 800 and 1000 ℃, respectively for 6 h and subsequently quenched in the water to investigate their thermal stability and phase transformation at high temperature. The microstructure and mechanical properties of the samples were investigated by scanning electron microscopy, X-ray diffraction, compressive and hardness tests. It was found that the as-cast CoFeNi2V0.5Nb0.75 HEAs showed a eutectic microstructure with alternating fcc solid solution phase and Fe2Nb-type Laves phase. The NbNi4-type intermetallic phase appeared when the heat-treated temperature was higher than 600 ℃. With increasing quenching temperature, the volume fraction of the NbNi4-type intermetallic phase increased while that of the eutectic regions decreased. The sample quenched at 800 ℃ showed the most excellent comprehensive mechanical properties; its fracture strength, yield strength and plastic strain were as high as 2586.76 MPa, 2075.18 MPa and 16.73%, respectively. Moreover, the eutectic CoFeNi2V0.5Nb0.75 HEAs exhibited apparent age hardening, especially quenched at 700 ℃, the hardness reached up to the maximum value of HV 727.52.
The influences of slight amount of B element on the microstructure and properties of AlCoCrFeNiBx high entropy alloys(x = 0,0.01,…,0.09 and 0.1,mole fraction) were investigated.The AlCoCrFeNi high entropy alloy exhibits equiaxed grain structures with obvious composition segregation.However,with the addition of B element,the alloys exhibit dendrite structures.Inside the dendrites,spinodal decomposition structure can be clearly observed.With the addition of B element,the crystal structures change from(B2 + BCC) to(B2 + BCC + FCC) structures,and the hardness firstly increases from HV 486.7 to HV 502.4,then declines to HV 460.7(x ≥ 0.02).The compressive fracture strength firstly shows a trend of increasing,and then declining(x ≥ 0.08).The coercive forces and the specific saturation magnetizations of the alloys decrease as B addition contents increase,the decreasing coercive forces show a better soft magnetic behavior.
In order to study the wear behavior of different kinds of contact wires,the dry sliding wear behaviors of Cu-Sn,Cu-Ag and Cu-Mg alloys prepared by up-drawn continuous casting and followed continuous extrusion were studied.The research was tested on a block-on-ring wear tester.The results indicate that the friction coefficient is remarkably influenced by the formation of a continuous tribofilm,which consists of oxidation film.The abrasion,adhesion,oxidation and plastic deformation are observed.Oxidation and abrasion wear mechanisms dominate at the lower sliding velocity and load.The combination of oxidation and adhesion play leading roles with the increasing load and velocity.Plastic deformation is detected under higher applied load and sliding velocities.