Efficient red organic light-emitting device consisted of a compound fluorescent-phosphor-sensitized emission layer was fabricated. A novel red fluorescent dye, 3-(dicyanomethylene)-5,5-dimethyl-1-(4-dimethylamino-styryl) cyclohexene (DCDDC), and a green phosphorescent dye, fac tris(2-phenylpyridine) iridium [Ir(ppy)3] were codoped into a host material 4,4'-N,N'-dicarbazolebiphe-nyl (CBP). By adjusting the component ratio of doping system, a series of devices with different concentration proportion of Ir(ppy)3:DCDDC were constructed. The results demonstrated that the device with 0.2 wt% DCDDC had a maximum power effi-ciency (ηp) of 2.12 lm/W at a current density of 0.1 mA/cm2, which was about 38% higher than that of conventional fluorescent device. When at a current density of 4 mA/cm2 (100 cd/m2) and 52 mA/cm2 (1000 cd/m2), the ηp percentage was about 160% and 143% higher than that of conventional device, respectively. A stable red light emission at a peak of 615 nm with Commissions Internationale de l'Eclairage coordinates near the region of (0.56, 0.42) in a wide bias range was also obtained. The improved performances were attributed to the efficient multiple-stage energy transfer from the host to the guest and the suppression of loss mechanism.
The influence of an ultrathin 4-(dicyanomethylene)-2-t-butyl-6-(1,1,7,7-tetramethyljulolidyl-9-enyl)-4H-pyran (DCJTB) fluorescent dye layer at donor/acceptor heterojunction on the performance of small-molecule organic photovoltaic (OPV) cell is studied.The structure of OPV cell is of indium-tin oxide (ITO)/copper phthalocyanine (CuPc)/DCJTB/fullerene (C 60)/bathophenanthroline (Bphen)/Ag.The results show that open circuit voltage (V OC) increases to 0.57 V as the film thickness of DCJTB layer increases from 0.2 to 2.0 nm.By using an equivalent circuit model,the enhancement of V OC is found to be attributed to the reduced reverse saturation current density (J S) which is due to the lower highest occupied molecular orbital (HOMO) level in DCJTB than that in CuPc.Also,the short circuit current density (J SC) is affected when the DCJTB layer becomes thicker,resulting from the high series resistance R S A due to the low charge carrier mobility of fluorescent red dye.
