The corrosion behaviors of the isolated short and vertical long scale Q235 B steel in a simulated tidal zone were studied by electrochemical impedance spectroscopy(EIS) monitoring and corrosion weight loss calculation in an experimental indoor simulating trough.The results show that the corrosion rate of the isolated short scale Q235 B steel in the tidal zone acquired by the EIS agrees with the corrosion weight loss result.The corrosion rates of the short scale steel are in the order of middle tidal zone > the central zone between the middle tidal zone and low tidal zone > high tidal zone > low tidal zone.The fastest corrosion rate in the middle tidal zone is attributed to the longest wet time in a tidal cycle.According to the comparison of corrosion weight loss between the vertical long scale and isolated short scale specimens,the corrosion rate of vertical long scale specimens of Q235 B steel is lower than that of the isolated short scale specimens in the tidal zone,but the result is contrary in the immersion zone.
Electrochemical impedance spectroscopy(EIS) and film thickness measurement have been employed to study the atmospheric corrosion of a weathering steel covered with a thin electrolyte layer in a simulated coastal–industrial atmosphere. The results indicate that the corrosion rate is a function of the covered electrolyte thickness and the wet/dry cycle. Within each wet/dry cycle, the increased corrosion rate is related to the increased Cl-and SO2-4concentration and an enhancement of oxygen diffusion rate with the evaporation of the electrolyte. In addition, the corrosion rate increases during the initial corrosion stage and then decreases as the wet/dry cycle proceeds. Moreover, one mathematical approach based on the numerical integration method to obtain corrosion mass loss of steel from the measurements of EIS has been developed, and this would be useful for the development of indoor simulated atmospheric corrosion tests.
