The powders of RE2Co17(RE=Y, Ce, Nd, Ho, Er) and Ho x Co100–x(x=6, 8, 10, 12) alloys were prepared by the arc melting method and high-energy ball mill process. The compositions and morphologies of the alloys were characterized by X-ray diffraction(XRD) and scanning electron microscopy(SEM), and the microwave absorbing properties were studied by a vector network analyzer. The results showed that the alloy of Y2Co17 had better absorbing properties at low frequencies and its lowest reflectivity value was –9.5 d B at 3.8 GHz. The lowest reflectivity value of Ho2Co17 alloy was –13.7 d B at 7.02 GHz and it obtained large absorbing bandwidth. Reflectivity value less than –5 d B was from 5.1 to 10.2 GHz. When x=6 and x=8, the alloys of Ho x Co100–x consisted of Ho2Co17 phase and Co phase. They had good radar absorbing properties. With increase in Ho content, the minimum reflectivity value worsened and the absorbing peak frequency shifted toward higher frequencies. But when x=12, the absorbing peak frequency shifted toward lower frequencies but the minimum reflectivity value worsened.
NdFeCo magnetic powder was prepared by the process of smelting,high-energy ball milling and oxidation heat treating.The effects of oxidation heat treatment and Co content on phase composition and microwave absorbing properties of NdFeCo magnetic powder were investigated by an X-ray diffractometer(XRD)and vector network analyzer.The minimum reflectivity of Nd23.25Fe36.75Co40 powder before oxidation heat treatment was-6.2 dB,and that of oxidized powder decreased to-14.0 dB.The microwave absorbing properties of NdFeCo magnetic powder could be improved effectively by oxidation heat treatment.With the increase of Co content,the Fe2O3 reduced and the Nd2O3 increased;Fe3Co7 phase appeared when the content of Co increased to 40%(mass ratio);the absorption peak was found to move towards lower frequency region first,and then it moved towards a higher frequency region.Nd23.25Fe66.75Co10 powder had better comprehensive properties in absorbing microwave in the frequency band of 3-13 GHz.The value of minimum reflectivity and absorption peak frequency,when the coating thickness(d)was 1.8 mm,were-19.7 dB and 4.8 GHz,respectively.
