The title nanocrystalline powders were prepared by sol-gel method, the influences of grain size on crystal structure were investigated by XRD and DSC techniques. The experiment results show that the tetragonal ferroelectric phase content of the powders and the Curie temperature Tc are increased with the increase of grain size. When the grain size is less than 34. 7nm, crystal structure of the particle changes into cubic paraelectric phase and the transition of ferro-paraelectric phase disappears as well.
The solubility properties of ZnSO4-Met/Phe/His-H2O systems at 25℃ in thewhole concentration range have been investigated by phase equilibrium method, and the corresponding equilibrium diagrams have been constructed. Under the direction of the phase equilibrium result, the compounds of ZnSO4 with Met, Phe and His which are not reported in literatures have been prepared and characterized.
