The extraction of potassium from potash feldspar by NaCl, CaCl 2, SrCl 2 and BaCl 2 has been investigated as function of salt kind and calcination temperature. The phase compositions of potash feldspar and its calcinated, and water insoluble substances of NaCl, CaCl 2 co-calcinated potash feldspar were analyzed by XRD. The experiment results showed that the order of ion exchange extraction of potassium was Na +>Ca 2+>Sr 2+>Ba 2+, and at calcination temperature over the melting points of NaCl or CaCl 2, the two salts gave potassium ion-exchange degree >90% much greater than that calcinated with other salts.