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黄薇文

作品数:10 被引量:76H指数:6
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10 条 记 录,以下是 1-10
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长江入东海的化学物质输送特点被引量:9
1994年
本文基于1984~1987年间对长江下游及河口地区的4个航次的观测和分析结果,讨论了常量与重金属元素的浓度及输送模式。与世界上其他大河流相比长江重金属元素的浓度较低,相反常量元素含量较高,这与中国大陆强烈的化学剥蚀和相对较低的人类活动水平有关。在淡水-咸水混合过程中大多数颗粒态元素呈稳定态分布,特别是当元素的绝对浓度用A1或Sc校正后尤为明显。溶解常量元素呈保守性,因此它们的输送通常可根据河流末端浓度与流量或含沙量之积来估算。大多数溶解态痕量元素是非保守的,在估算它们的外输通量时应根据元素在河口的分布曲线乘以相应的增高或减小因子。
黄薇文张经
关键词:长江化学物质
阳极溶出伏安法测定海水中的砷被引量:3
1980年
本文研究了用阳极溶出伏安法测定海水中的砷(Ⅲ)和总砷。用玻碳电极同位镀金直接测定砷(Ⅲ);用过硫酸钾消化后,亚硫酸钠将砷(Ⅴ)还原成砷(Ⅲ)而测得总砷。本方法的检出限达3×10^(-10)M。回收率砷(Ⅲ)为106±4%,总砷为101±11%。样品经过简单的预处理能得到较好的重现性。
黄薇文赫崇利李福荣王庆璋李静
关键词:阳极溶出伏安法海水化学
应用微分脉冲阳极溶出伏安法研究河口介质中的铅和镉
1984年
河口环境中微量金属的研究工作还是很年轻的,其原因之一是因为在七十年代以前所报道的微量金属含量几乎完全是无效的。
黄薇文
关键词:微分脉冲阳极溶出伏安法海水化学
青岛地区大气沉降物的化学成分研究——Ⅰ.微量元素被引量:18
1991年
用原子吸收分光光度法测定了青岛地区大气干、湿沉降物中微量元素Co、Cr、Cu、Fe、Mn、Ni、Ph、Zn等,并测定了雨水的 pH。分析表明,雨水中微量元素的溶解态浓度与降雨量是反相关,且高于海水和世界河流平均值,表明青岛地区雨水对海洋可能成为一个污染源。酸雨促进了大气颗粒物的溶解,改变了元素溶解态与颗粒态之间的配比,对大气、海洋环境系统构成一定程度的危害。在此基础上本文讨论了干、湿沉降物的浓度变化和通量,并就干沉降与南黄海沉积物、青岛地区雨水溶解态与未污染区域的溶解态元素之间的潜在关联以及冬、夏季雨水中溶解态、颗粒态化学要素和大气干沉降的浓度差别,进行了对比分析。
刘素美黄薇文张经王菊英纪晓文
关键词:空气污染沉降物化学成分
阳极溶出伏安法测定水体中的铅和镉被引量:2
1980年
工业废水中的铅、镉等排入河道、海湾、造成了水质的污染,近年来对水体中的痕量及超痕量的铅和镉的测定有不少报导,原子吸收分光光度法虽有较高的灵敏度,但仪器昂贵;常用的萃取比色法,手续繁杂,干扰多,灵敏度不高,因此在环境污染检测中也不适用。铅和镉都有良好的极谱行为,但是经典极谱、示波极谱和方波极谱等灵敏度都不够高,对环境化学中测定镉和铅是不适用的。
黄薇文赫崇利钟霞云
关键词:阳极溶出伏安法海水化学
青岛地区大气沉降物中化学成分研究 2.常量组分被引量:14
1993年
用原子吸收和分光光度法测定了青岛大气干、湿沉降物中K、Na、Ca、Mg的含量及雨水中的阴离子SO42-、Ci-、NO3-、NO2-、PO43-、SiO32-等含量和pH。 分析表明,雨水中溶解态的金属元素和阴离子的浓度与降雨量反相关,其中金属元素浓度高于偏远沿海地区雨水中金属元素的浓度,而低于内陆雨水。近岸地区雨水中K/Cl、Na/Cl、Ca/Cl、Mg/Cl比相近,均高于大洋水的相应比值,而雨水中溶解态金属元素浓度低于海水和河水;阴离子浓度与河水相近,除SO42-、Cl-较低外,NO3-、NH4+、PO43-远高于海水。 在此基础上我们计算了青岛大气中K、Na、Ca、M9的干、湿沉降通量,结果表明湿沉降通量高于干沉降通量,湿沉降对于物质向大洋的输送起更重要的作用。
刘素美黄薇文张经王俊鹤纪晓文王菊英
关键词:沉降物化学成分
黄河口及邻近海域中悬浮体的分布特征和季节性变化被引量:12
1985年
The results of the suspended material measurement in the Huanghe River Estuary show that the silt movement in the estuary is different during summer and winter. The centric water-mass in Bohai Sea enters the Laizhou Bay, which makes the fresh water occupy the head of Laizhou Bay and prevents the silt from spveading to the sea.The disturbing of wind in winter makes the sediment resuspend which results in the high content of suspended materials in the water. The distribution of suspended materials and salinity in summer indicate that because of its own momentum, the silt from the Huanghe River will go ahead out of the river mouth and the effect of centric water-mass in the middle Bohai Sea is relatively small in summer. The distributions of suspended materials in the mid and bottom layer water during different seasons show that the primary direction of the siltl movement in the estuary is towards NE, whice coincides with the movement of residual current.Our paper also presents the size distribution of suspended materials.According to the data, we consider that the silt from Huanghe River moves mainly in the surface layer and the Huanghe River Estuary belongs to weak mixing estuary.
张经黄薇文刘敏光
关键词:黄河口悬浮体
黄河口及其毗邻海区底质中重金属的分布规律及季节性变化被引量:1
1985年
Heavy metals (Cu, Pb, Zn, Mn, Fe, Cr, Ni) in the sediment from Huanghe River Estuary and the adjacent areas were analyzed using Model WFX-IA AAS. The eoneentrationsof these elements are: Cu 9-32ppm,Pb 24-44ppm,Zn 41-105ppm, Mn 500-700ppm, Fe 2.1-3.0%, Cr 50-71ppm, Ni 24-72ppm. There are relatively close correlations among the distribution of the heavy metals, suspended materials and salinity. The distribution of heavy metals in summer are similar to that in winter, except Pb. It is believed that the higher concentration results from the increasing of water discharge,silt content and the decreasing of particle size in the summer. Pb is easily absorbed and carried in the suspended materials,which, perhaps, is another reason that the concentration of Pb is higher in summer.
李静陈淑珠刘敏光杨淑海黄薇文张经
关键词:黄河口底质重金属
黄河口地区沉积物中若干地球化学参数及地球化学环境被引量:10
1985年
This paper is concerned with the distibuticn of seme geochemical factors in sediments from Huanghe River Estuary,such as Eh,pH,Fe/Fe and the ratio of elementsp which show the characteristics of sedimentation in the estuary.According to the physical-chemistry principle the diagram of FeS2-Fe3O4-Fe2O3 system is made to indicate the coexistence and the tranform among minerals.
黄薇文张经杨作升
关键词:黄河口海洋沉积物地球化学参数沉积环境EH
黄河口底质中重金属的存在形式被引量:15
1985年
Ten samples from the Huanghe River Estuary were analysed to separate the heavy metals (Cu, Pb, Zn, Cr, Ni, Fe, Mn, Cd) into following phases: (1) adsorbed to materials, (2) bound to carbonates, (3) Fe-Mn oxides, (4) organic matters, (5) residual. The contents of the heavy metals in residue fraction account to the main part of the total concentrations. The concentrations of the heavy metals adsorbed on the materials are very low, and the heavy metals bound to Fe-Mn oxides are relatively stable, making up 10-20 percent of the t otal concentrations, which indicates that there is almost no heavy metal pollution in the estuary. The content of Pb, Mn bound to carbonates are rather high, Pb makes up 18-42 percent, Mn 22-63 percent of the total concentration, which are caused by geological process and coincide with the high content of carbonates in the loess. Cu is concentrated in organic matter indicating the strong complexation abilily of copper with organic matter. The distribution of all the eight elements are not all the same. The order of their progressive decreasing are written as follows: (1) Cu, Cr, Hi, Fe, Zn: Ⅴ>Ⅳ≥Ⅲ>Ⅱ>Ⅰ; (2) Pb, Cd: Ⅴ>Ⅱ>Ⅲ≥Ⅳ Ⅰ;(3) Mn:Ⅱ>Ⅴ>Ⅲ>Ⅳ>Ⅰ.
黄薇文张经刘敏光邱丽璇陈长景
关键词:黄河口重金属底质海水化学
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