Spectrum analysis of the plasma has over the years been growing both in methods and instrument, which makes it become a widely used non-contact detection method, without disturbing the arc plasma itself. With noticeable developments in the industry application of the method, a need for careful analysis of the plasma with both time and space identification is desirable. Therefore, a spectral measurement system is developed in this paper for diagnosing arc plasma with time and space identification. With a new hollow probe scanning method, the instrument can be used to provide information like energy distribution of plasma, temperature within the arc plasma, which are of great significance with the requirement of space identification. Furthermore, the system can also be used to capture the instant state of the arc plasma with the synchronic triggering system, which uses high speed photo and electrical signal as the time criterion. The industry applications prove that the system works well for online detection of the arc plasma.