[Objective] This study aimed to investigate the existing forms and bioaccessibility of vanadium（V） from soil and mineral of Panzhihua region.[Method] The representative Xigeda soil and vanadium-titanium magnetite were collected from Panzhihua region to determine the existing forms of vanadium from soil and mineral;in vitro bionic digestion model was established to measure the bioaccessibility of vanadium.[Result] The dissolved concentrations of vanadium from farmland,mining area and vanadium-titanium magnetite in gastric juice were respectively 5.02,9.50 and 3.88 mg/kg,and the bioaccessibility ranged from 0.09% to 3.00%;the dissolved concentrations of vanadium in intestinal juice were respectively 2.98,5.43 and 4.49 mg/kg,and the bioaccessibility ranged from 0.10% to 1.78%.The content of vanadium in various existing forms varied significantly,the contents of vanadium in non-specific adsorption state and specific adsorption state were low,but residual content was completely high,which accounted for 75.06%,95.32% and 86.27% of the total content of vanadium in samples.[Conclusion] Bioaccessibility of dissolved vanadium in gastric juice was higher than that in small intestinal juice.Vanadium from soil and mineral was difficult to generate morphological transformation and migration,which was the main reason for low bioaccessibility.
