The compound [H2（teta）]2+·2Cl-·3H2O （teta=meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane）was synthesized and characterized by elementary analysis and the structure was determined by single-crystal X-ray diffraction.The crystal belongs to triclinic,space group Pī with a=7.8364（16）,b=8.3607（13）,c=9.4762（15）?,α=61.900（12）,β=78.970（16）,γ=80.008（16）°,V=535.06（16）?3,Z=1,ρcalc=1.277g/cm3,F（000）=226.The macrocylic tetraamine cation contains two protonated secondary amine N atoms and two secondary amine N atoms.The water molecules are distinguished by their inequality in structure formation.They are involved in different types of intermolecular hydrogen bonding in the crystal lattice.
The title compound [Ni(acac)2(dadpm)]∞ (acac=acetylacetonate, dadpm=4 ,4′-diaminodiphenylmethane) was synthesized from Ni(acac)2·2H2O with dadpm in DMF. The structure was characterized by elemental analysis, IR spectroscopy, the rmal analysis and single-crystal X-ray diffraction. X-ray analysis revealed that the central Ni atom is at a center of symmetry, and is octahedrally coordinated by four O atoms from two acac anions and two N atoms from two dadpm ligands. Ea ch dadpm ligand, which has a two-fold axis passing through its methylene C atom, bridges two Ni atoms to form a 1D polymeric chain. Neighboring chains connect v ia H bonding interactions to generate a 2D network. It crystallizes in the monoc linic system, space group P2/c with a=0.556 79(7), b=0.896 06(12), c=2.187 3(3) nm, β=94.942(3)°, V=1.087 2(3) nm3, Z=2, Dc=1.390 g·cm-3, F(000)=480, Mr=455. 17, μ(Mo Kα)=0.924 mm-1, R(F)=0.036 0, wR(F 2)=0.101 0, S=1.013. CCDC: 254565 .
The manganese(Ⅲ) complex [Mn (acacen) {N (CN)2}]n [H2acacen =bis (acetylacetone)ethylenediimine] has been synthesized and the structure has been determined. The complex forms a one-dimensional chain structure via the bidentate bridge ligandμ1,5-[N(CN)2]- linking [Mn(acacen)] moiety. The magnetic property of the compound (75～300 K) shows the existence of an antiferromagnetic exchange interaction among paramagnetic centers along the chain. CCDC: 244940.
The uranyl complex [UO2（PMBP）2（DMDBU）]（HPMBP=1-phenyl-3-methy1-4-benzoyl-pyrazolone-5,DMDBU=N,N′-dimethyl-N,N′-dibenzenyl-urea）was synthesized and characterized.The structure was determined by single X-ray diffraction analysis.The crystal belongs to triclinic system,space group P（1）-.The crystallographic data are:a=9.5947（10）,b=12.0531（11）,c=20.002（2）,α=77.167（7）,β=80.090（8）,γ=75.870（7）°,V=2170.1（4）3,Z=2,F（000）=1052,Mr=164.92,Dc=1.630 Mg/m3,μ=3.800mm-1,R1=0.0409,wR2=0.0770.In the crystal,the uranyl ion is coordinated by four oxygen atoms from two PMBP ligands and one oxygen atoms from one DMDBU to form a distorted pentagonal-bipyramid geometry.
The cadmium complex[Cd(PMBP)2(EtOH)2](HPMBP =1-phenyl-3-methyl-4-benzoyl-pyrazolone-5)wassynthesized and characterized by IR and thermogravimetric analysis.The structure was determined by single X-ray diffraction anal-ysis.The crystal belongs to triclinic system,space group P 1.The crystallographic data are:a =9.121(4),b =10.193(5),c =10.895(5),α=107.085(4),β=108.239(4),γ=104.028(2)°,V=855.0(6) 3,Z =1,F(000) =390,Mr =759.12,Dc=1.474 Mg/m3,μ=0.692 mm-1,R1=0.0312 and wR2=0.0836.In the crystal Cd(Ⅱ)ion is coordinated by four oxygen atomsfrom two PMBP ligands and two oxygen atoms from two solvent EtOHmolecules to form a distorted octahedron geometry.
